يعرض 71 - 80 نتائج من 1,137 نتيجة بحث عن '"Ma, Zhiyong"', وقت الاستعلام: 1.02s تنقيح النتائج
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    دورية أكاديمية
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    دورية أكاديمية

    المصدر: Chinese Journal of Chemistry; Mar2024, Vol. 42 Issue 6, p611-616, 6p

    مستخلص: Comprehensive Summary: Mechanochromic polymers based on non‐covalent changes have attracted much attention recently. Herein, we report the impact of inter/intramolecular hydrogen bonds on polymer mechanochromism from the excited state intramolecular proton transfer (ESIPT) process. PhMz‐NH2‐OH and PhMz=2A are designed and obtained by simple and high‐yield synthesis, and are connected into polyurethane and poly(methyl acrylate‐co‐2‐ethylhexyl acrylate), respectively. In the initial state, the PhMz‐NH2‐OH@PU sample shows blue fluorescence from the excited enol form (E*) excitons, owing to intermolecular hydrogen bonds that interrupt the ESIPT reactions but the PhMz=2A@PMA‐2‐EA sample expresses cyan fluorescence belonging to the excited keto form (K*) emission, implying that the intramolecular hydrogen bonds matter. Furthermore, under stretching, external force can tune the emission of the PhMz=2A@PMA‐2‐EA sample from K* to E* state. Though external force can putatively still promote a bond rotation, ESIPT reactions remain equivalently interrupted in both the relaxed and stressed states in a hydrogen‐bond donating environment. DFT calculation confirms the force‐induced increase in dihedral angle for the transition of ESIPT‐on/off. Thus, PhMz‐NH2‐OH@PU and PhMz=2A@PMA‐2‐EA showed disparate initial ESIPT states and further different responses/sensitivity to force. This study reports a novel and efficient strategy for enriching mechanochromic investigation and extending the applications of ESIPT reactions. [ABSTRACT FROM AUTHOR]

    : Copyright of Chinese Journal of Chemistry is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

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    دورية أكاديمية

    المصدر: Advanced Energy Materials; Feb2024, Vol. 14 Issue 5, p1-10, 10p

    مستخلص: Polymers play a crucial role in promoting the progress of high‐performance inverted perovskite solar cells (PSCs). However, few polymers have simultaneously achieved defect passivation and device encapsulation in PSCs. Herein, a telechelic silicone polymer (poly(dimethylsiloxane‐co‐methylsiloxane acrylate) [PDMA]) is introduced, which possesses crosslinking capability to enable structure regulation through a condensation reaction. By leveraging the advantages of the polymers before and after crosslinking, a synergistic strategy of defect healing and device encapsulation for PSCs is developed via the application of the targeted polymer. PDMA as additives anchors tightly at the grain boundaries (GBs) and bridges the perovskite grains, achieving defect passivation and GBs crosslinking, increasing the efficiency of inverted PSCs from 22.32% to 24.41%. Crosslinked PDMA (CPDMA) is used as an encapsulant to encapsulate the entire device, enabling non‐destructive encapsulation at room temperature and inhibiting perovskite degradation under photothermal aging. Remarkably, the PDMA‐modified device with CPDMA encapsulation maintains 98% of its initial efficiency after 1200 h under continuous illumination at 55 ± 5 °C and retains 95% of its original efficiency after 1000 h of damp heat testing, meeting one of the IEC61215:2016 standards. [ABSTRACT FROM AUTHOR]

    : Copyright of Advanced Energy Materials is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

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