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1دورية أكاديمية
المصدر: Polymers, Vol 16, Iss 10, p 1330 (2024)
مصطلحات موضوعية: reactivity ratios, terpolymerization, polymerization kinetics, 2-methylene-1,3-dioxepane (MDO), butyl acrylate, vinyl acetate, Organic chemistry, QD241-441
الوصف: This investigation introduces the first estimation of ternary reactivity ratios for a butyl acrylate (BA), 2-methylene-1,3-dioxepane (MDO), and vinyl acetate (VAc) system at 50 °C, with an aim to develop biodegradable pressure-sensitive adhesives (PSAs). In this study, we applied the error-in-variables model (EVM) to estimate reactivity ratios. The ternary reactivity ratios were found to be r12 = 0.417, r21 = 0.071, r13 = 4.459, r31 = 0.198, r23 = 0.260, and r32 = 55.339 (BA/MDO/VAc 1/2/3), contrasting with their binary counterparts, which are significantly different, indicating the critical need for ternary system analysis to accurately model multicomponent polymerization systems. Through the application of a recast Alfrey–Goldfinger model, this investigation predicts the terpolymer’s instantaneous and cumulative compositions at various conversion levels, based on the ternary reactivity ratios. These predictions not only provide crucial insights into the incorporation of MDO across different initial feed compositions but also offer estimates of the final terpolymer compositions and distributions, underscoring their potential in designing compostable or degradable polymers.
وصف الملف: electronic resource
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2دورية أكاديمية
المؤلفون: Iraj MOHAMMADFAM, Maryam MOVAFAGH, Saeid BASHIRIAN
المصدر: Iranian Journal of Public Health, Vol 45, Iss 3 (2016)
مصطلحات موضوعية: Public aspects of medicine, RA1-1270
الوصف: No Abstract.
وصف الملف: electronic resource