دورية أكاديمية
Square-micrometer-sized, free-standing organometallic sheets and their square-centimeter-sized multilayers on solid substrates.
| العنوان: | Square-micrometer-sized, free-standing organometallic sheets and their square-centimeter-sized multilayers on solid substrates. |
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| المؤلفون: | Zheng Z; Laboratory of Polymer Chemistry, Department of Materials, Swiss Federal Institute of Technology, ETH Zürich, HCI J 541, Wolfgang Pauli Strasse 10, 8093, Zürich, Switzerland., Ruiz-Vargas CS, Bauer T, Rossi A, Payamyar P, Schütz A, Stemmer A, Sakamoto J, Schlüter AD |
| المصدر: | Macromolecular rapid communications [Macromol Rapid Commun] 2013 Nov; Vol. 34 (21), pp. 1670-80. Date of Electronic Publication: 2013 Sep 23. |
| نوع المنشور: | Journal Article; Research Support, Non-U.S. Gov't |
| اللغة: | English |
| بيانات الدورية: | Publisher: Wiley-VCH Country of Publication: Germany NLM ID: 9888239 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1521-3927 (Electronic) Linking ISSN: 10221336 NLM ISO Abbreviation: Macromol Rapid Commun Subsets: MEDLINE |
| أسماء مطبوعة: | Publication: 2002- : Weinheim, Germany : Wiley-VCH Original Publication: Basel ; Oxford, CT : Hüthig & Wepf, c1994- |
| مواضيع طبية MeSH: | Ferrous Compounds/*chemistry , Pyridines/*chemistry, Models, Molecular ; Molecular Structure ; Particle Size ; Surface Properties |
| مستخلص: | Oligofunctional terpyridine-based monomers are spread at an air/water interface, where they are connected with transition metal salts such as Fe(II) into mechanically coherent monolayer sheets of macroscopic dimension. The conversions of these processes are determined by XPS for several monomer/metal ion combinations. The sheets are transferred onto TEM grids, the 20 × 20 square micrometer sized holes of which can be spanned. AFM indentation experiments provide in-plane elastic moduli which are compared with naturally occurring sheets such as graphene. The new organometallic sheets are also used to create multilayer assemblies on square centimeter length scales on solid substrates. Finally some directions are provided where this research can lead to in future and where its application potential lies. (© 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.) |
| فهرسة مساهمة: | Keywords: 2D dimensional materials; coordination chemistry; elastic modulus; interfacial polymerization; surface analysis |
| المشرفين على المادة: | 0 (Ferrous Compounds) 0 (Pyridines) |
| تواريخ الأحداث: | Date Created: 20131012 Date Completed: 20141102 Latest Revision: 20131104 |
| رمز التحديث: | 20231215 |
| DOI: | 10.1002/marc.201300624 |
| PMID: | 24115363 |
| قاعدة البيانات: | MEDLINE |
Full Text Finder | تدمد: | 1521-3927 |
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| DOI: | 10.1002/marc.201300624 |