دورية أكاديمية

ZIF-8 Membrane Permselectivity Modification by Manganese(II) Acetylacetonate Vapor Treatment.

التفاصيل البيبلوغرافية
العنوان: ZIF-8 Membrane Permselectivity Modification by Manganese(II) Acetylacetonate Vapor Treatment.
المؤلفون: Hayashi M; Department of Chemical and Biomolecular Engineering, & Institute for NanoBioTechnology, Johns Hopkins University, 3400 N. Charles Street, Baltimore, MD, 21218, USA.; Science & Innovation Center, Mitsubishi Chemical Corporation, 1000 Kamoshida-cho, Aoba-ku, Yokohama-shi, Kanagawa, 227-8502, Japan., Lee DT; Department of Chemical and Biomolecular Engineering, & Institute for NanoBioTechnology, Johns Hopkins University, 3400 N. Charles Street, Baltimore, MD, 21218, USA., de Mello MD; Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, NY, 11973, USA.; Catalysis Center for Energy Innovation, University of Delaware, Newark, DE, 19716, USA., Boscoboinik JA; Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, NY, 11973, USA.; Materials Science and Chemical Engineering Department, Stony Brook University, Stony Brook, NY, 11790, USA., Tsapatsis M; Department of Chemical and Biomolecular Engineering, & Institute for NanoBioTechnology, Johns Hopkins University, 3400 N. Charles Street, Baltimore, MD, 21218, USA.; Catalysis Center for Energy Innovation, University of Delaware, Newark, DE, 19716, USA.; Applied Physics Laboratory, Johns Hopkins University, 11100 Johns Hopkins Road, Laurel, MD, 20723, USA.
المصدر: Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2021 Apr 19; Vol. 60 (17), pp. 9316-9320. Date of Electronic Publication: 2021 Mar 12.
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: Wiley-VCH Country of Publication: Germany NLM ID: 0370543 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1521-3773 (Electronic) Linking ISSN: 14337851 NLM ISO Abbreviation: Angew Chem Int Ed Engl Subsets: PubMed not MEDLINE; MEDLINE
أسماء مطبوعة: Publication: <2004-> : Weinheim : Wiley-VCH
Original Publication: Weinheim/Bergstr. : New York, : Verlag Chemie ; Academic Press, c1962-
مستخلص: Vapor-phase treatment of ZIF-8 membranes with manganese(II) acetylacetonate (Mn(acac) 2 ) allows permselectivity tuning. Propylene/propane selectivity increases from 31 to 210 after the Mn(acac) 2 treatment at 165 °C for 30 min, while selectivities increase from 14.6 to 242 for H 2 /CH 4 , from 2.9 to 38 for CO 2 /CH 4 , from 2.4 to 29 for CO 2 /N 2 , and from 2.9 to 7.5 for O 2 /N 2 , after Mn(acac) 2 treatment at 175 °C for 30 min. Stable equimolar propylene/propane mixture selectivity of 165 at ambient temperature and 4 bar equimolar feed with a propylene flux of 8.3×10 -4  mol m -2  s -1 is established. A control experiment excludes thermal treatment alone causing these changes. XPS analysis reveals the presence of Mn(acac) 2 on the outer surface of the vapor-treated ZIF-8 membranes while no other changes are detectable by X-ray diffraction and infrared spectroscopy.
(© 2021 Wiley-VCH GmbH.)
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معلومات مُعتمدة: DE-SC0021212 Basic Energy Sciences; DE-SC0021304 Basic Energy Sciences; DE-SC0001004 Basic Energy Sciences; DE-SC0012704 U.S. Department of Energy
فهرسة مساهمة: Keywords: ZIF-8 membranes; gas separation; metal-organic frameworks; postsynthetic treatment; vapor-phase metal-organic treatment
تواريخ الأحداث: Date Created: 20210122 Latest Revision: 20210413
رمز التحديث: 20240628
DOI: 10.1002/anie.202100173
PMID: 33481308
قاعدة البيانات: MEDLINE