دورية أكاديمية
Keggin-type polyoxometalate 1 : 1 complexes of Pb(II) and Bi(III): experimental, theoretical and luminescence studies.
| العنوان: | Keggin-type polyoxometalate 1 : 1 complexes of Pb(II) and Bi(III): experimental, theoretical and luminescence studies. |
|---|---|
| المؤلفون: | Mukhacheva AA; Nikolaev Institute of Inorganic Chemistry, 3 Akad. Lavrentiev Ave. 630090, Russia. abramov@niic.nsc.ru., Asanova T; Nikolaev Institute of Inorganic Chemistry, 3 Akad. Lavrentiev Ave. 630090, Russia. abramov@niic.nsc.ru., Ryzhikov MR; Nikolaev Institute of Inorganic Chemistry, 3 Akad. Lavrentiev Ave. 630090, Russia. abramov@niic.nsc.ru., Sukhikh TS; Nikolaev Institute of Inorganic Chemistry, 3 Akad. Lavrentiev Ave. 630090, Russia. abramov@niic.nsc.ru., Kompankov NB; Nikolaev Institute of Inorganic Chemistry, 3 Akad. Lavrentiev Ave. 630090, Russia. abramov@niic.nsc.ru., Yanshole VV; International Tomography Center, Institutskaya str. 3a, 630090, Novosibirsk, Russia and Novosibirsk State University, Pirogova str. 1, 630090, Novosibirsk, Russia., Berezin AS; Nikolaev Institute of Inorganic Chemistry, 3 Akad. Lavrentiev Ave. 630090, Russia. abramov@niic.nsc.ru., Gushchin AL; Nikolaev Institute of Inorganic Chemistry, 3 Akad. Lavrentiev Ave. 630090, Russia. abramov@niic.nsc.ru., Abramov PA; Nikolaev Institute of Inorganic Chemistry, 3 Akad. Lavrentiev Ave. 630090, Russia. abramov@niic.nsc.ru., Sokolov MN; Nikolaev Institute of Inorganic Chemistry, 3 Akad. Lavrentiev Ave. 630090, Russia. abramov@niic.nsc.ru. |
| المصدر: | Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2021 May 25; Vol. 50 (20), pp. 6913-6922. |
| نوع المنشور: | Journal Article |
| اللغة: | English |
| بيانات الدورية: | Publisher: Royal Society of Chemistry Country of Publication: England NLM ID: 101176026 Publication Model: Print Cited Medium: Internet ISSN: 1477-9234 (Electronic) Linking ISSN: 14779226 NLM ISO Abbreviation: Dalton Trans Subsets: PubMed not MEDLINE; MEDLINE |
| أسماء مطبوعة: | Original Publication: Cambridge, UK : Royal Society of Chemistry, c2003- |
| مستخلص: | Bi3+ and Pb2+ uptake by a monolacunary Keggin-type [PW11O39]7- anion leads to the formation of [PW11O39Bi]4- and [PW11O39Pb]5- complexes with a stereochemically active lone pair at the incorporated heterometal. The two complexes were isolated as (TBA)4[PW11O39Bi] (1) and (TBA)5[PW11O39Pb] (2) and characterized by 31P and 183W NMR spectroscopy, high-resolution electrospray mass-spectrometry (HR-ESI-MS) and cyclic voltammetry (CV). EXAFS and XANES data confirm the unchanged oxidation state and ψ-square pyramidal geometry of Bi3+ and Pb2+ in 1 and 2. DFT calculations were used in order to (i) confirm the absence of ligands attached to the heterometal sites in both complexes and localize the lone pair, and (ii) assign all signals in the 183W NMR spectra. Complexes 1 and 2 demonstrate photoluminescence (PL). A reversible change in the PL spectra of both complexes in the presence of water vapor has been detected. On the contrary, PL data for sandwich-type ((CH3)4N)4K3[H4(PW11O39)2Bi]·25H2O (3) do not show sensitivity to water vapor. |
| تواريخ الأحداث: | Date Created: 20210430 Latest Revision: 20210525 |
| رمز التحديث: | 20231215 |
| DOI: | 10.1039/d1dt00499a |
| PMID: | 33928982 |
| قاعدة البيانات: | MEDLINE |
كن أول من يترك تعليقا!