دورية أكاديمية
Solvent-free bottom-up patterning of zeolitic imidazolate frameworks.
| العنوان: | Solvent-free bottom-up patterning of zeolitic imidazolate frameworks. |
|---|---|
| المؤلفون: | Miao Y; Department of Chemical and Biomolecular Engineering & Institute for NanoBioTechnology, Johns Hopkins University, Baltimore, MD, USA., Lee DT; Department of Chemical and Biomolecular Engineering & Institute for NanoBioTechnology, Johns Hopkins University, Baltimore, MD, USA., de Mello MD; Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, NY, USA.; Catalysis Center for Energy Innovation, University of Delaware, Newark, DE, USA., Ahmad M; Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, NY, USA.; Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, NY, USA., Abdel-Rahman MK; Department of Chemistry, Johns Hopkins University, Baltimore, MD, USA., Eckhert PM; Department of Chemistry, Johns Hopkins University, Baltimore, MD, USA., Boscoboinik JA; Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, NY, USA.; Department of Materials Science and Chemical Engineering, Stony Brook University, Stony Brook, NY, USA., Fairbrother DH; Department of Chemistry, Johns Hopkins University, Baltimore, MD, USA., Tsapatsis M; Department of Chemical and Biomolecular Engineering & Institute for NanoBioTechnology, Johns Hopkins University, Baltimore, MD, USA. tsapatsis@jhu.edu.; Applied Physics Laboratory, Johns Hopkins University, Laurel, MD, USA. tsapatsis@jhu.edu. |
| المصدر: | Nature communications [Nat Commun] 2022 Jan 20; Vol. 13 (1), pp. 420. Date of Electronic Publication: 2022 Jan 20. |
| نوع المنشور: | Journal Article |
| اللغة: | English |
| بيانات الدورية: | Publisher: Nature Pub. Group Country of Publication: England NLM ID: 101528555 Publication Model: Electronic Cited Medium: Internet ISSN: 2041-1723 (Electronic) Linking ISSN: 20411723 NLM ISO Abbreviation: Nat Commun Subsets: PubMed not MEDLINE; MEDLINE |
| أسماء مطبوعة: | Original Publication: [London] : Nature Pub. Group |
| مستخلص: | Patterning metal-organic frameworks (MOFs) at submicrometer scale is a crucial yet challenging task for their integration in miniaturized devices. Here we report an electron beam (e-beam) assisted, bottom-up approach for patterning of two MOFs, zeolitic imidazolate frameworks (ZIF), ZIF-8 and ZIF-67. A mild pretreatment of metal oxide precursors with linker vapor leads to the sensitization of the oxide surface to e-beam irradiation, effectively inhibiting subsequent conversion of the oxide to ZIFs in irradiated areas, while ZIF growth in non-irradiated areas is not affected. Well-resolved patterns with features down to the scale of 100 nm can be achieved. This developer-free, all-vapor phase technique will facilitate the incorporation of MOFs in micro- and nanofabrication processes. (© 2022. The Author(s).) |
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| معلومات مُعتمدة: | DE-SC0021212 U.S. Department of Energy (DOE); DE-SC0021304 U.S. Department of Energy (DOE); DE-SC0012704 U.S. Department of Energy (DOE) |
| تواريخ الأحداث: | Date Created: 20220121 Latest Revision: 20221023 |
| رمز التحديث: | 20231215 |
| مُعرف محوري في PubMed: | PMC8776825 |
| DOI: | 10.1038/s41467-022-28050-z |
| PMID: | 35058452 |
| قاعدة البيانات: | MEDLINE |
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