دورية أكاديمية

Synthesis, characterization and application of a novel polyazo dye as a universal acid-base indicator.

التفاصيل البيبلوغرافية
العنوان: Synthesis, characterization and application of a novel polyazo dye as a universal acid-base indicator.
المؤلفون: Naime J; Chemistry Discipline, School of Science, Engineering and Technology, Khulna University Khulna-9208 Bangladesh s.mamun@ku.ac.bd., Mamun MSA; Chemistry Discipline, School of Science, Engineering and Technology, Khulna University Khulna-9208 Bangladesh s.mamun@ku.ac.bd., Aly Saad Aly M; Department of Electrical and Computer Engineering at Georgia Tech Shenzhen Institute (GTSI), Tianjin University Shenzhen Guangdong 518052 China., Maniruzzaman M; Department of Chemistry, Khulna University of Engineering and Technology Khulna-9203 Bangladesh., Badal MMR; Department of Chemistry, Khulna University of Engineering and Technology Khulna-9203 Bangladesh., Karim KMR; Chemistry Discipline, School of Science, Engineering and Technology, Khulna University Khulna-9208 Bangladesh s.mamun@ku.ac.bd.
المصدر: RSC advances [RSC Adv] 2022 Oct 03; Vol. 12 (43), pp. 28034-28042. Date of Electronic Publication: 2022 Oct 03 (Print Publication: 2022).
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: Royal Society of Chemistry Country of Publication: England NLM ID: 101581657 Publication Model: eCollection Cited Medium: Internet ISSN: 2046-2069 (Electronic) Linking ISSN: 20462069 NLM ISO Abbreviation: RSC Adv Subsets: PubMed not MEDLINE
أسماء مطبوعة: Original Publication: Cambridge [England] : Royal Society of Chemistry, [2011]-
مستخلص: A novel organic polyazo dye is synthesized by the diazotization of aromatic aniline, followed by coupling it with sulfanilic acid and N , N -dimethylaniline. Characterization was done by 1 H-NMR, 13 C-NMR, and FTIR spectroscopy. Differential scanning calorimetry (DSC) reveals that phase transition for this molecule is exothermic. The optical band gap is estimated from the absorption cutoff point using UV-Visible spectroscopy. Thermal gravimetric analysis (TGA) addresses the thermal stability of the molecule and is found to be at ∼250 °C. The structure of the synthesized molecule is analogous to that of methyl orange and contains three azo groups. These three azo groups help accept more than two protons and provide two p K a values when diprotic acid or a mixture of acids is used in different titrations. Specifically, when a polybasic acid is in strong base titration, the p K a values were found to be 3.5 and 9.1. Moreover, for strong base and (strong + weak) acid mixture titration, the p K a values are found to be 9.2 and 3.3. Furthermore, the p K a values are found to be 8.6 and 2.8 for (strong and weak) base mixture and (strong and weak) acid mixture titration, respectively. Owing to its increased proton accepting capacity, it can be found in the two pH ranges of 2.1-3.8 for orange color and 8.2-9.8 for yellow color, thus indicating a unique property as a universal indicator for acid-base titration. The dissociation constant of this dye is found to be 3.4 × 10 -6 , determined in a mixed aqueous solution of 10 wt% ethanol, and a linear relationship between p K a and pH is observed in this solvent system.
Competing Interests: Authors declare no conflict of interest.
(This journal is © The Royal Society of Chemistry.)
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تواريخ الأحداث: Date Created: 20221102 Latest Revision: 20221104
رمز التحديث: 20221213
مُعرف محوري في PubMed: PMC9527568
DOI: 10.1039/d2ra04930a
PMID: 36320250
قاعدة البيانات: MEDLINE
الوصف
تدمد:2046-2069
DOI:10.1039/d2ra04930a