دورية أكاديمية
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Copolymerization of Carbonyl Sulfide and Propylene Oxide via a Heterogeneous Prussian Blue Analogue Catalyst with High Productivity and Selectivity.

التفاصيل البيبلوغرافية
العنوان: Copolymerization of Carbonyl Sulfide and Propylene Oxide via a Heterogeneous Prussian Blue Analogue Catalyst with High Productivity and Selectivity.
المؤلفون: Ullah Khan M; State Key Laboratory of Motor Vehicle Biofuel Technology, International Research Center for X Polymers, Department of Polymer Science and Engineering, Zhejiang University, 310027, Hangzhou, P. R. China., Ullah Khan S; Hefei National Laboratory for Physical Science at the Microscale, School of Life Sciences, University of Science and Technology of China, 230027, Hefei, P. R. China., Cao X; State Key Laboratory of Motor Vehicle Biofuel Technology, International Research Center for X Polymers, Department of Polymer Science and Engineering, Zhejiang University, 310027, Hangzhou, P. R. China., Usman M; Key Laboratory of Macromolecular Synthesis and Functionalization (Ministry of Education), International Research Center for X Polymers, Department of Polymer Science and Engineering, Zhejiang University, 310027, Hangzhou, P. R. China., Yue X; State Key Laboratory of Motor Vehicle Biofuel Technology, International Research Center for X Polymers, Department of Polymer Science and Engineering, Zhejiang University, 310027, Hangzhou, P. R. China., Ghaffar A; Advanced Materials Research Center, Zhejiang University-University of Illinois at Urbana-Champaign Institute (ZJU-UIUC), 718 East Haizhou Road, Haining, 314400, Zhejiang, P. R. China., Hassan M; Advanced Materials Research Center, Zhejiang University-University of Illinois at Urbana-Champaign Institute (ZJU-UIUC), 718 East Haizhou Road, Haining, 314400, Zhejiang, P. R. China., Zhang C; State Key Laboratory of Motor Vehicle Biofuel Technology, International Research Center for X Polymers, Department of Polymer Science and Engineering, Zhejiang University, 310027, Hangzhou, P. R. China., Zhang X; State Key Laboratory of Motor Vehicle Biofuel Technology, International Research Center for X Polymers, Department of Polymer Science and Engineering, Zhejiang University, 310027, Hangzhou, P. R. China.; Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering, 030013, Shanxi, P. R. China.
المصدر: Chemistry, an Asian journal [Chem Asian J] 2023 Jan 03; Vol. 18 (1), pp. e202201050. Date of Electronic Publication: 2022 Nov 24.
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: Wiley-VCH Country of Publication: Germany NLM ID: 101294643 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1861-471X (Electronic) Linking ISSN: 1861471X NLM ISO Abbreviation: Chem Asian J Subsets: MEDLINE
أسماء مطبوعة: Original Publication: Weinheim, Germany : Wiley-VCH, c2006-
مواضيع طبية MeSH: Polymers* , Cobalt*, Catalysis
مستخلص: This study demonstrates the superiority of a stable and well-defined heterogeneous cobalt hexacyanocobaltate (Co 3 [Co(CN) 6 ] 2 ), a typical cobalt Prussian Blue Analogue (CoCo-PBA) that catalyzes the copolymerization of carbonyl sulfide (COS) and propylene oxide (PO) to produce poly(propylene monothiocarbonate)s (PPMTC). The number-average molecular weights of the PPMTC were 66.4 to 139.4 kg/mol, with a polydispersity of 2.0-3.9. The catalyst productivity reached 1040 g polymer/g catalyst (12.0 h). The oxygen-sulfur exchange reaction (O/S ER), which would generate random thiocarbonate and carbonate units, was effectively suppressed, and thus the selectivity of the monothiocarbonate over carbonate linkages was up to >99%. It was shown that no cyclic thiocarbonate byproduct was produced during the heterogeneous catalysis of COS/PO copolymerization using CoCo-PBA as the catalyst. The content of monothiocarbonate and ether units in the copolymer chain could be regulated by tuning the feeding amount of COS.
(© 2022 Wiley-VCH GmbH.)
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معلومات مُعتمدة: 51973190 National Science Foundation of China; 2020R52006 Zhejiang Provincial Department of Science and Technology; Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering
فهرسة مساهمة: Keywords: Carbonyl sulfide; Co3[Co(CN)6]2; Copolymerization; Heterogeneous catalysis; Poly(propylene monothiocarbonate)s
المشرفين على المادة: Y4Y7NYD4BK (propylene oxide)
TLE294X33A (ferric ferrocyanide)
871UI0ET21 (carbonyl sulfide)
0 (Polymers)
3G0H8C9362 (Cobalt)
تواريخ الأحداث: Date Created: 20221107 Date Completed: 20230105 Latest Revision: 20230111
رمز التحديث: 20240829
DOI: 10.1002/asia.202201050
PMID: 36342176
قاعدة البيانات: MEDLINE
الوصف
تدمد:1861-471X
DOI:10.1002/asia.202201050