| المؤلفون: |
Yu X; Novosibirsk State University, 2 Pirogov Str., 630090, Novosibirsk, Russia. cluster@niic.nsc.ru.; Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Lavrentiev Ave., 630090, Novosibirsk, Russia., Ryadun AA; Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Lavrentiev Ave., 630090, Novosibirsk, Russia., Kovalenko KA; Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Lavrentiev Ave., 630090, Novosibirsk, Russia., Guselnikova TY; Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Lavrentiev Ave., 630090, Novosibirsk, Russia., Ponomareva VG; Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch of the Russian Academy of Sciences, 18 Kutateladze Str., 630090, Novosibirsk, Russia., Potapov AS; Novosibirsk State University, 2 Pirogov Str., 630090, Novosibirsk, Russia. cluster@niic.nsc.ru.; Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Lavrentiev Ave., 630090, Novosibirsk, Russia., Fedin VP; Novosibirsk State University, 2 Pirogov Str., 630090, Novosibirsk, Russia. cluster@niic.nsc.ru.; Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Lavrentiev Ave., 630090, Novosibirsk, Russia. |
| مستخلص: |
Lanthanide metal-organic frameworks (Ln-MOFs) combine the lanthanide luminescence characteristics and the advantages of porous materials, which can be used in various research fields by exploring their multifunctional properties. A three-dimensional water-stable and high-temperature resistant Eu-MOF [Eu(H 2 O)(HL)]·0.5MeCN·0.25H 2 O (H4L = 4-(3,5-dicarboxyphenoxy)isophthalic acid), demonstrating a high photoluminescence quantum yield, was synthesized and structurally characterized. In terms of luminescence, the Eu-MOF exhibits excellent selectivity and quenching sensing for Fe 3+ (LOD = 4.32 μM) and ofloxacin, as well as color modulation with Tb 3+ and La 3+ to develop white LED components with high illumination efficiency (color rendering index, CRI = 90). On the other hand, narrow one-dimensional channels of the Eu-MOF decorated with COOH groups enable a rare reverse adsorption selectivity in a CO 2 /C 2 H 2 gas mixture. In addition, the protonated carboxyl groups in the Eu-MOF provide an efficient conducting platform for proton transfer with a conductivity value of 8 × 10 -4 S cm -1 at 50 °C and RH 100%. |
