دورية أكاديمية

A Coordination-Driven Self-Assembly and NIR Photothermal Conversion Study of Organometallic Handcuffs.

التفاصيل البيبلوغرافية
العنوان: A Coordination-Driven Self-Assembly and NIR Photothermal Conversion Study of Organometallic Handcuffs.
المؤلفون: Lu X; College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China., Huang JJ; Luoyang Institute of Science and Technology, Luoyang 471023, China., Chen T; College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China., Zheng J; College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China.; College of Materials and Chemical Engineering, China Three Gorges University, Yichang 443002, China., Liu M; College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China., Wang XY; College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China., Li YX; College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China., Niu X; College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China.; College of Science, Shihezi University, Shihezi 832003, China., Dang LL; College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China.
المصدر: Molecules (Basel, Switzerland) [Molecules] 2023 Sep 27; Vol. 28 (19). Date of Electronic Publication: 2023 Sep 27.
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: MDPI Country of Publication: Switzerland NLM ID: 100964009 Publication Model: Electronic Cited Medium: Internet ISSN: 1420-3049 (Electronic) Linking ISSN: 14203049 NLM ISO Abbreviation: Molecules Subsets: PubMed not MEDLINE; MEDLINE
أسماء مطبوعة: Original Publication: Basel, Switzerland : MDPI, c1995-
مستخلص: Due to their fascinating topological structures and application prospects, coordination supramolecular complexes have continuously been studied by scientists. However, the controlled construction and property study of organometallic handcuffs remains a significant and challenging research subject in the area of supramolecular chemistry. Hence, a series of tetranuclear organometallic and heterometallic handcuffs bearing different size and metal types were rationally designed and successfully synthesized by utilizing a quadridentate pyridyl ligand (tetra-(3-pyridylphenyl)ethylene) based on three Cp*Rh (Cp* = η 5 -C 5 Me 5 ) fragments bearing specific longitudinal dimensions and conjugated planes. These results were determined with single-crystal X-ray diffraction analysis technology, ESI-MS NMR spectroscopy, etc. Importantly, the photoquenching effect of Cp* groups and the discrepancy of intermolecular π-π stacking interactions between building block and half-sandwich fragments promote markedly different photothermal conversion results. These results will further push the synthesis of topological structures and the development of photothermal conversion materials.
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معلومات مُعتمدة: 22101108 and 22102068 National Natural Science Foundation of China; 212300410209 Natural Science Foundation of Henan Province; 232300421083 Natural Science Foundation for Excellent Young Scholars of Henan Province; 22A150016 Key Scientific Research Projects of Higher Education of He'nan Province
فهرسة مساهمة: Keywords: coordination-driven self-assembly; half-sandwich fragment; organometallic handcuffs; photothermal conversion
تواريخ الأحداث: Date Created: 20231014 Latest Revision: 20231020
رمز التحديث: 20231215
مُعرف محوري في PubMed: PMC10574444
DOI: 10.3390/molecules28196826
PMID: 37836669
قاعدة البيانات: MEDLINE
الوصف
تدمد:1420-3049
DOI:10.3390/molecules28196826