دورية أكاديمية
أعرض في EDS

Bisphenol A degradation by chlorine dioxide (ClO 2 ) and S(IV)/ClO 2 process: Mechanism, degradation pathways and toxicity assessment.

التفاصيل البيبلوغرافية
العنوان: Bisphenol A degradation by chlorine dioxide (ClO 2 ) and S(IV)/ClO 2 process: Mechanism, degradation pathways and toxicity assessment.
المؤلفون: Wang Z; School of Civil and Environmental Engineering, Harbin Institute of Technology (Shenzhen), Shenzhen, 518055, China. Electronic address: wangzhuoyue242@163.com., Li J; School of Civil and Environmental Engineering, Harbin Institute of Technology (Shenzhen), Shenzhen, 518055, China; Shenzhen Key Laboratory of Water Resource Utilization and Environmental Pollution Control, Shenzhen, 518055, China; State Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin, 150090, China., Song W; School of Civil and Transportation Engineering, Guangdong University of Technology, Guangzhou, 510006, China., Yang J; Key Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education, Institute of Environmental Research at Greater Bay, Guangzhou University, Guangzhou, 510006, China., Dong W; School of Civil and Environmental Engineering, Harbin Institute of Technology (Shenzhen), Shenzhen, 518055, China; Shenzhen Key Laboratory of Water Resource Utilization and Environmental Pollution Control, Shenzhen, 518055, China; State Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin, 150090, China., Zhang X; School of Civil and Environmental Engineering, Harbin Institute of Technology (Shenzhen), Shenzhen, 518055, China. Electronic address: zhangxiaolei@hit.edu.cn.
المصدر: Environmental pollution (Barking, Essex : 1987) [Environ Pollut] 2023 Dec 15; Vol. 339, pp. 122736. Date of Electronic Publication: 2023 Oct 12.
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: Elsevier Applied Science Publishers Country of Publication: England NLM ID: 8804476 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1873-6424 (Electronic) Linking ISSN: 02697491 NLM ISO Abbreviation: Environ Pollut Subsets: MEDLINE
أسماء مطبوعة: Original Publication: Barking, Essex, England : Elsevier Applied Science Publishers, c1987-
مواضيع طبية MeSH: Chlorine Compounds*/toxicity , Chlorine Compounds*/chemistry , Water Purification* , Water Pollutants, Chemical*/toxicity , Water Pollutants, Chemical*/analysis, Oxides/toxicity ; Oxides/chemistry ; Phenols/toxicity ; Oxidation-Reduction ; Chlorine/chemistry
مستخلص: Recently, it has been reported that chlorine dioxide (ClO 2 ) and (bi)sulfite/ClO 2 showed excellent performance in micropollutant removal from water; however, the degradation mechanisms and application boundaries of the two system have not been identified. In this study, bisphenol A (BPA) was chosen as the target contaminant to give multiple comparisons of ClO 2 and S(IV)/ClO 2 process regarding the degradation performance of contaminant, generation of reactive species, transformation of products and toxicity variation. Both ClO 2 and S(IV)/ClO 2 can degrade BPA within 3 min. The BPA degradation mechanism was mainly based on direct oxidation in ClO 2 process while it was attributed to radicals (especially SO 4 ·- ) generation in S(IV)/ClO 2 process. Meanwhile, the effect of pH and coexisting substances (Cl - , Br - , HCO 3 - and HA) were evaluated. It was found that ClO 2 preferred the neutral and alkaline condition and S(IV)/ClO 2 preferred the acidic condition for BPA degradation. An unexpected speed-up of BPA degradation was observed in ClO 2 process in the presence of Br - , HCO 3 - and HA. In addition, the intermediate products in BPA degradation were identified. Three exclusive products were found in ClO 2 process, in which p-benzoquinone was considered to be the reason of the acute toxicity increase in ClO 2 process.
Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
(Copyright © 2023 Elsevier Ltd. All rights reserved.)
فهرسة مساهمة: Keywords: (bi)sulfite; Advanced oxidation process; Chlorine oxide radical; Endocrine disruptors; Sulfate radical
المشرفين على المادة: 8061YMS4RM (chlorine dioxide)
MLT3645I99 (bisphenol A)
0 (Oxides)
0 (Chlorine Compounds)
0 (Phenols)
4R7X1O2820 (Chlorine)
0 (Water Pollutants, Chemical)
تواريخ الأحداث: Date Created: 20231014 Date Completed: 20231120 Latest Revision: 20231120
رمز التحديث: 20231215
DOI: 10.1016/j.envpol.2023.122736
PMID: 37838321
قاعدة البيانات: MEDLINE
الوصف
تدمد:1873-6424
DOI:10.1016/j.envpol.2023.122736