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Sorption and mobility assessment of tembotrione in soils of upper, trans and middle Gangetic plain zones of India.

التفاصيل البيبلوغرافية
العنوان: Sorption and mobility assessment of tembotrione in soils of upper, trans and middle Gangetic plain zones of India.
المؤلفون: Ghoshal D; Division of Agricultural Chemicals, ICAR-Indian Agricultural Research Institute, New Delhi, India., Dixit M; Sardar Vallabhbhai Patel University of Agriculture and Technology, Meerut, India., Narayanan N; Division of Agricultural Chemicals, ICAR-Indian Agricultural Research Institute, New Delhi, India., Saini P; Division of Agricultural Chemicals, ICAR-Indian Agricultural Research Institute, New Delhi, India., Kumar A; Division of Agricultural Chemicals, ICAR-Indian Agricultural Research Institute, New Delhi, India., Banerjee T; Division of Agricultural Chemicals, ICAR-Indian Agricultural Research Institute, New Delhi, India., Singh N; Division of Agricultural Chemicals, ICAR-Indian Agricultural Research Institute, New Delhi, India., Gupta S; Division of Agricultural Chemicals, ICAR-Indian Agricultural Research Institute, New Delhi, India.
المصدر: Biomedical chromatography : BMC [Biomed Chromatogr] 2024 Aug; Vol. 38 (8), pp. e5939. Date of Electronic Publication: 2024 Jun 17.
نوع المنشور: Journal Article
اللغة: English
بيانات الدورية: Publisher: Wiley Country of Publication: England NLM ID: 8610241 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1099-0801 (Electronic) Linking ISSN: 02693879 NLM ISO Abbreviation: Biomed Chromatogr Subsets: MEDLINE
أسماء مطبوعة: Publication: 1990- : Chichester : Wiley
Original Publication: London : Heyden & Son, c1986-1990
مواضيع طبية MeSH: Soil Pollutants*/chemistry , Soil Pollutants*/analysis , Cyclohexanones*/chemistry , Cyclohexanones*/analysis, India ; Adsorption ; Soil/chemistry ; Tandem Mass Spectrometry/methods ; Chromatography, Liquid/methods ; Herbicides/chemistry ; Herbicides/analysis ; Linear Models ; Limit of Detection ; Reproducibility of Results ; Sulfones
مستخلص: The presence of undesired agrochemicals residues in soil and water poses risks to both human health and the environment. The behavior of pesticides in soil depends both on the physico-chemical properties of pesticides and soil type. This study examined the adsorption-desorption and leaching behavior of the maize herbicide tembotrione in soils of the upper (UGPZ), trans (TGPZ) and middle Gangetic plain zones of India. Soil samples were extracted using acetone followed by partitioning with dichloromethane, whereas liquid-liquid extraction using dichloromethane was used for aqueous samples. Residues of tembotrione and its metabolite TCMBA, {2-chloro-4-(methylsulfonyl)-3-[(2,2,2-trifluoroethoxy) methyl] benzoic acid}, were quantified using liquid chromatography-tandem mass spectrometry. The data revealed that tembotrione adsorption decreased with increasing pH and dissolved organic matter but increased with salinity. The maximum adsorption occurred at pH 4, 0.01 m sodium citrate and 4 g/L NaCl, with corresponding Freundlich constants of 1.83, 2.28 and 3.32, respectively. The hysteresis index <1 indicated faster adsorption than desorption. Leaching studies under different flow conditions revealed least mobility in UGPZ soil and high mobility in TGPZ soil, consistent with groundwater ubiquity scores of 4.27 and 4.81, respectively. Soil amendments decreased tembotrione mobility in the order: unamended > wheat straw ash > wheat straw > farm yard manure > compost. The transformation of tembotrione to TCMBA and its mobility in soil columns were also assessed.
(© 2024 John Wiley & Sons Ltd.)
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معلومات مُعتمدة: ICAR-IARI (JRF/SRF)
فهرسة مساهمة: Keywords: GUS; adsorption–desorption; hysteresis index; leaching; tembotrione
المشرفين على المادة: 0 (Soil Pollutants)
0 (Cyclohexanones)
WA5UZ202KS (tembotrione)
0 (Soil)
0 (Herbicides)
0 (Sulfones)
تواريخ الأحداث: Date Created: 20240617 Date Completed: 20240712 Latest Revision: 20240712
رمز التحديث: 20240712
DOI: 10.1002/bmc.5939
PMID: 38886169
قاعدة البيانات: MEDLINE
الوصف
تدمد:1099-0801
DOI:10.1002/bmc.5939