دورية أكاديمية
Capturing the Interplay Between TADF and RTP Through Mechanically Flexible Polymorphic Optical Waveguides.
| العنوان: | Capturing the Interplay Between TADF and RTP Through Mechanically Flexible Polymorphic Optical Waveguides. |
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| المؤلفون: | Vinod Kumar A; Advanced Photonic Materials and Technology Laboratory, School of Chemistry and Centre for Nanotechnology, University of Hyderabad, Prof. C. R. Rao Road, Gachibowli, Hyderabad, 500046, Telangana, India., Pattanayak P; Department of Chemical Sciences and Center for Advanced Functional Materials, Indian Institute of Science Education and Research, Kolkata, Mohanpur, 741246, West Bengal, India., Khapre A; Advanced Photonic Materials and Technology Laboratory, School of Chemistry and Centre for Nanotechnology, University of Hyderabad, Prof. C. R. Rao Road, Gachibowli, Hyderabad, 500046, Telangana, India., Nandi A; Department of Chemical Sciences and Center for Advanced Functional Materials, Indian Institute of Science Education and Research, Kolkata, Mohanpur, 741246, West Bengal, India., Purkayastha P; Department of Chemical Sciences and Center for Advanced Functional Materials, Indian Institute of Science Education and Research, Kolkata, Mohanpur, 741246, West Bengal, India., Chandrasekar R; Advanced Photonic Materials and Technology Laboratory, School of Chemistry and Centre for Nanotechnology, University of Hyderabad, Prof. C. R. Rao Road, Gachibowli, Hyderabad, 500046, Telangana, India. |
| المصدر: | Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2024 Jun 26, pp. e202411054. Date of Electronic Publication: 2024 Jun 26. |
| Publication Model: | Ahead of Print |
| نوع المنشور: | Journal Article |
| اللغة: | English |
| بيانات الدورية: | Publisher: Wiley-VCH Country of Publication: Germany NLM ID: 0370543 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1521-3773 (Electronic) Linking ISSN: 14337851 NLM ISO Abbreviation: Angew Chem Int Ed Engl Subsets: MEDLINE |
| أسماء مطبوعة: | Publication: <2004-> : Weinheim : Wiley-VCH Original Publication: Weinheim/Bergstr. : New York, : Verlag Chemie ; Academic Press, c1962- |
| مستخلص: | Polymorphism plays a pivotal role in generating a range of crystalline materials with diverse photophysical and mechanical attributes, all originating from the same molecule. Here, we showcase two distinct polymorphs: green (GY) emissive and orange (OR) emissive crystals of 5'-(4-(diphenylamino)phenyl)-[2,2'-bithiophene]-5-carbaldehyde (TPA-CHO). These polymorphs display differing optical characteristics, with GY exhibiting thermally activated delayed fluorescence (TADF) and OR showing room temperature phosphorescence (RTP). Additionally, both polymorphic crystals display mechanical flexibility and optical waveguiding capabilities. Leveraging the AFM-tip-based mechanophotonics technique, we position the GY optical waveguide at varying lengths perpendicular to the OR waveguide. This approach facilitates the exploration of the interplay between TADF and RTP phenomena by judiciously controlling the optical path length of crystal waveguides. Essentially, our approach provides a clear pathway for understanding and controlling the photophysical processes in organic molecular crystals, paving the way for advancements in polymorphic crystal-based photonic circuit technologies. (© 2024 Wiley-VCH GmbH.) |
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| معلومات مُعتمدة: | SERB-STR/2022/00011 Science and Engineering Research Board, New Delhi; CRG/2023/003911 Science and Engineering Research Board, New Delhi; CRG/2022/000006 Science and Engineering Research Board, New Delhi |
| فهرسة مساهمة: | Keywords: flexible crystals; mechanophotonics; optical waveguides; photophysical properties; polymorphism |
| تواريخ الأحداث: | Date Created: 20240626 Latest Revision: 20240812 |
| رمز التحديث: | 20240813 |
| DOI: | 10.1002/anie.202411054 |
| PMID: | 38924274 |
| قاعدة البيانات: | MEDLINE |
Full Text Finder | تدمد: | 1521-3773 |
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| DOI: | 10.1002/anie.202411054 |