التفاصيل البيبلوغرافية
| العنوان: |
Chiral Templating in a Hybrid Chromium Chloride Hydrate. |
| المؤلفون: |
Race JT; Department of Chemistry and Biochemistry, The Ohio State University, 100 W. 18th Avenue, Columbus, Ohio 43210, United States., Foster C; Department of Chemistry and Biochemistry, The Ohio State University, 100 W. 18th Avenue, Columbus, Ohio 43210, United States., Woodward PM; Department of Chemistry and Biochemistry, The Ohio State University, 100 W. 18th Avenue, Columbus, Ohio 43210, United States. |
| المصدر: |
Inorganic chemistry [Inorg Chem] 2024 Jul 04. Date of Electronic Publication: 2024 Jul 04. |
| Publication Model: |
Ahead of Print |
| نوع المنشور: |
Journal Article |
| اللغة: |
English |
| بيانات الدورية: |
Publisher: American Chemical Society Country of Publication: United States NLM ID: 0366543 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1520-510X (Electronic) Linking ISSN: 00201669 NLM ISO Abbreviation: Inorg Chem Subsets: MEDLINE |
| أسماء مطبوعة: |
Original Publication: [Easton, Pa.] American Chemical Society. |
| مستخلص: |
The synthesis and characterization of three new hybrid metal halide hydrates in which mer -[Cr III Cl 3 (H 2 O) 3 ] 0 cocrystallizes alongside α-methylbenzylammonium chloride are described. The enantiomorphic crystals, (( R )-(+)-α-methylbenzylammonium) 2 ( mer -[CrCl 3 (H 2 O) 3 ])Cl 2 (( R )- 1 ) and (( S )-(-)-α-methylbenzylammonium) 2 ( mer -[CrCl 3 (H 2 O) 3 ])Cl 2 (( S )- 1 ), have C 222 1 space group symmetry and show mirrored circular dichroism signals. The racemate, ( rac -α-methylbenzylammonium) 2 ( mer -[CrCl 3 (H 2 O) 3 ])Cl 2 (( rac )- 1 ), adopts a polar structure with Cm space group symmetry in which enantiomers are related by mirror planes within organic bilayers. Alongside detailed crystallography and magnetism of each compound, the optical properties of the mer -[Cr III Cl 3 (H 2 O) 3 ] 0 unit are revisited. Understanding the intermolecular forces that stabilize each of these crystal structures lends insights into crystal engineering methodologies for stabilizing noncentrosymmetric hybrid metal halides. |
| تواريخ الأحداث: |
Date Created: 20240704 Latest Revision: 20240704 |
| رمز التحديث: |
20240704 |
| DOI: |
10.1021/acs.inorgchem.4c02009 |
| PMID: |
38962962 |
| قاعدة البيانات: |
MEDLINE |
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