دورية أكاديمية
Trapping an Elusive Fe(IV)-Superoxo Intermediate Inside a Self-Assembled Nanocage in Water at Room Temperature.
| العنوان: | Trapping an Elusive Fe(IV)-Superoxo Intermediate Inside a Self-Assembled Nanocage in Water at Room Temperature. |
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| المؤلفون: | Gera R; Department of Chemical Sciences, Tata Institute of Fundamental Research, Mumbai 400005, India.; Department of Education in Science and Mathematics, Regional Institute of Education - Mysuru, NCERT, Mysuru 570006, India., De P; Department of Chemical Sciences, Indian Institute of Science Education and Research Kolkata, Mohanpur, West Bengal 741246, India., Singh KK; Chemical Engineering Division, CSIR-National Chemical Laboratory, Pune, Maharashtra 411008, India.; Chemistry Department, Indian Institute of Technology, Dharwad 580007, India., Jannuzzi SAV; Department of Inorganic Spectroscopy, Max Planck Institute for Chemical Energy Conversion, Stiftstr. 34-36, Mülheim an der Ruhr 45470, Germany., Mohanty A; Department of Chemical Sciences, Tata Institute of Fundamental Research, Mumbai 400005, India., Velasco L; Instituto de Ciencia de Materiales de Madrid Consejo Superior de Investigaciones Científicas Sor Juana Inés de la Cruz, 3, Madrid 28049, Spain., Kulbir; Department of Chemistry, Indian Institute of Science Education and Research (IISER), Tirupati 517507, India., Kumar P; Department of Chemistry, Indian Institute of Science Education and Research (IISER), Tirupati 517507, India., Marco JF; Instituto de Quimica Fisica Blas Cabrera, Consejo Superior de Investigaciones Científicas, Serrano 119, Madrid 28006, Spain., Nagarajan K; Department of Chemical Sciences, Tata Institute of Fundamental Research, Mumbai 400005, India., Pecharromán C; Instituto de Ciencia de Materiales de Madrid Consejo Superior de Investigaciones Científicas Sor Juana Inés de la Cruz, 3, Madrid 28049, Spain., Rodríguez-Pascual PM; Instituto de Ciencia de Materiales de Madrid Consejo Superior de Investigaciones Científicas Sor Juana Inés de la Cruz, 3, Madrid 28049, Spain., DeBeer S; Department of Inorganic Spectroscopy, Max Planck Institute for Chemical Energy Conversion, Stiftstr. 34-36, Mülheim an der Ruhr 45470, Germany., Moonshiram D; Instituto de Ciencia de Materiales de Madrid Consejo Superior de Investigaciones Científicas Sor Juana Inés de la Cruz, 3, Madrid 28049, Spain., Gupta SS; Department of Chemical Sciences, Indian Institute of Science Education and Research Kolkata, Mohanpur, West Bengal 741246, India., Dasgupta J; Department of Chemical Sciences, Tata Institute of Fundamental Research, Mumbai 400005, India. |
| المصدر: | Journal of the American Chemical Society [J Am Chem Soc] 2024 Aug 07; Vol. 146 (31), pp. 21729-21741. Date of Electronic Publication: 2024 Jul 30. |
| نوع المنشور: | Journal Article |
| اللغة: | English |
| بيانات الدورية: | Publisher: American Chemical Society Country of Publication: United States NLM ID: 7503056 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1520-5126 (Electronic) Linking ISSN: 00027863 NLM ISO Abbreviation: J Am Chem Soc Subsets: PubMed not MEDLINE; MEDLINE |
| أسماء مطبوعة: | Publication: Washington, DC : American Chemical Society Original Publication: Easton, Pa. [etc.] |
| مستخلص: | Molecular cavities that mimic natural metalloenzymes have shown the potential to trap elusive reaction intermediates. Here, we demonstrate the formation of a rare yet stable Fe(IV)-superoxo intermediate at room temperature subsequent to dioxygen binding at the Fe(III) site of a (Et |
| تواريخ الأحداث: | Date Created: 20240730 Latest Revision: 20240807 |
| رمز التحديث: | 20240807 |
| DOI: | 10.1021/jacs.4c05849 |
| PMID: | 39078020 |
| قاعدة البيانات: | MEDLINE |
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