دورية أكاديمية

Enhanced photocatalytic performance of CeO2-TiO2 nanocomposite for degradation of crystal violet dye and industrial waste effluent.

التفاصيل البيبلوغرافية
العنوان: Enhanced photocatalytic performance of CeO2-TiO2 nanocomposite for degradation of crystal violet dye and industrial waste effluent.
المؤلفون: Zahoor, Mehvish, Arshad, Amara, Khan, Yaqoob, Iqbal, Mazhar, Bajwa, Sadia Zafar, Soomro, Razium Ali, Ahmad, Ishaq, Butt, Faheem K., Iqbal, M. Zubair, Wu, Aiguo, Khan, Waheed S.
المصدر: Applied Nanoscience; Jun2018, Vol. 8 Issue 5, p1091-1099, 9p
مصطلحات موضوعية: PHOTOCATALYSIS, CERIUM oxides, TITANIUM oxides, NANOCOMPOSITE materials, DYES & dyeing, INDUSTRIAL wastes
مستخلص: This study presents the synthesis of CeO2-TiO2 nanocomposite and its potential application for the visible light-driven photocatalytic degradation of model crystal violet dye as well as real industrial waste water. The ceria-titania (CeO2-TiO2) nanocomposite material was synthesised using facile hydrothermal route without the assistance of any template molecule. As-prepared composite was characterised by SEM, TEM, HRTEM, XRD, XPS for surface features, morphological and crystalline characters. The formed nanostructures were determined to possess crystal-like geometrical shape and average size less than 100 nm. The as-synthesised nanocomposite was further investigated for their heterogeneous photocatalytic potential against the oxidative degradation of CV dye taken as model pollutant. The photo-catalytic performance of the as-synthesised material was evaluated both under ultra-violet as well as visible light. Best photocatalytic performance was achieved under visible light with complete degradation (100%) exhibited within 60 min of irradiation time. The kinetics of the photocatalytic process were also considered and the reaction rate constant for CeO2-TiO2 nanocomposite was determined to be 0.0125 and 0.0662 min−1 for ultra-violet and visible region, respectively. In addition, the as-synthesised nanocomposite demonstrated promising results when considered for the photo-catalytic degradation of coloured industrial waste water collected from local textile industry situated in Faisalabad region of Pakistan. Enhanced photo-catalytic performance of CeO2-TiO2 nanocomposite was proposed owing to heterostructure formation leading to reduced electron-hole recombination. [ABSTRACT FROM AUTHOR]
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