التفاصيل البيبلوغرافية
| العنوان: |
Gold Vinylidenes as Useful Intermediates in Synthetic Organic Chemistry. |
| المصدر: |
Synthesis; 2019, Vol. 51 Issue 5, p1087-1099, 13p |
| مصطلحات موضوعية: |
ORGANIC synthesis, ORGANIC chemistry, VINYLIDENE compounds, ALKYNE synthesis, ALKYNES |
| مستخلص: |
Gold vinylidenes have recently emerged as useful intermediates in synthetic organic chemistry. These species, which can principally be accessed by a 1,2-migration process from a gold-activated alkyne or by dual gold catalysis on a diyne substrate, can react with nucleophilic partners or by C–H insertion to produce a variety of functionalized (poly)cyclic compounds. This short review covers the synthetic approaches developed so far to access gold vinylidenes and the different reactivities these species can exhibit. 1 Introduction 2 1,2-Migration Processes 3 Dual Gold Catalysis 4 Other Processes 5 Conclusion [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
Complementary Index |
