التفاصيل البيبلوغرافية
العنوان: |
Subphthalocyanine-sensitized TiO2 photocatalyst for photoelectrochemical and photocatalytic hydrogen evolution. |
المؤلفون: |
Celil Yüzer, A., Genc, Eminegül, Harputlu, Ersan, Yanalak, Gizem, Aslan, Emre, Ocakoglu, Kasim, Hatay Patir, Imren, Ince, Mine |
المصدر: |
Dalton Transactions: An International Journal of Inorganic Chemistry; 9/28/2020, Vol. 49 Issue 36, p12550-12554, 5p |
مصطلحات موضوعية: |
HYDROGEN evolution reactions, PHOTOCATALYSTS, HYDROGEN, CARBOXYLIC acids, OPTICAL properties, PHOTOSENSITIZERS |
مستخلص: |
A series of SubPcs comprising a carboxylic acid anchoring group at the peripheral (SubPcs 1, 2) or axial position (SubPc 3) were synthesized and used as sensitizers for photocatalytic H2 production, for the first time. SubPc 3/TiO2 shows the best photocatalytic activity with a hydrogen evolution rate of 1396 μmol h−1, which is much higher than that of SubPcs 1 and 2 (771 and 658 μmol g−1, respectively). This work clearly shows that considering their optical and redox properties, SubPcs are promising candidates for light-driven water splitting systems. [ABSTRACT FROM AUTHOR] |
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قاعدة البيانات: |
Complementary Index |