التفاصيل البيبلوغرافية
| العنوان: |
Heterobimetallic uranyl(VI) alkoxides of lanthanoids: formation through simple ligand exchange. |
| المؤلفون: |
Grödler, Dennis, Weidemann, Martin L., Lichtenberg, Andreas, Greven, Tobias, Nickstadt, Robin, Haydo, Malek, Wickleder, Mathias, Klein, Axel, Johrendt, Dirk, Mathur, Sanjay, Zegke, Markus, Raauf, Aida |
| المصدر: |
Chemical Communications; 1/18/2022, Vol. 58 Issue 6, p835-838, 4p |
| مصطلحات موضوعية: |
ALKOXIDES, CHEMICAL bond lengths, BIMETALLIC catalysts, ATOMS |
| مستخلص: |
Lanthanoid and actinoid silylamides are versatile starting materials. Herein we show how a simple ligand exchange with tert-butanol leads to the formation of the first trimeric heterobimetallic uranyl(VI)–lanthanoid(III) alkoxide complexes. The μ3 coordination of the endogenous uranyl oxo atom results in a significant elongation of the bond length and a significant deviation from the linear uranyl arrangement. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
Complementary Index |
