دورية أكاديمية
Gas-phase formation of Grignard-type organolanthanide (III) ions RLnCl3-: The influences of lanthanide center and hydrocarbyl group.
العنوان: | Gas-phase formation of Grignard-type organolanthanide (III) ions RLnC |
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المؤلفون: | Meixian Yang, Zhixin Xiong, Yangjuan Li, Xiuting Chen, Wei Zhou |
المصدر: | Rapid Communications in Mass Spectrometry: RCM; 6/15/2023, Vol. 37 Issue 11, p1-8, 8p |
مصطلحات موضوعية: | IONS, RARE earth metals, CHLORIDE ions, GRIGNARD reagents, DENSITY functional theory, ORGANOMAGNESIUM compounds |
مستخلص: | Rationale: Compared with organomagnesium compounds (Grignard reagents), the Grignard-type organolanthanides (III) exhibit several utilizable differences in reactivity. However, the fundamental understanding of Grignard-type organolanthanides (III) is still in its infancy. Decarboxylation of metal carboxylate ions is an effective method to obtain organometallic ions that are well suited for gasphase investigation using electrospray ionization (ESI) mass spectrometry in combination with density functional theory (DFT) calculations. Methods: The (RCO |
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قاعدة البيانات: | Complementary Index |
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