التفاصيل البيبلوغرافية
| العنوان: |
Superhydrophobic MOFs with enhanced catalytic activity for chemical fixation of CO2. |
| المؤلفون: |
Liu, Shuo, Gao, Ming-Liang, Li, Chen-Ning, Liu, Lin, Han, Zheng-Bo |
| المصدر: |
Dalton Transactions: An International Journal of Inorganic Chemistry; 10/28/2023, Vol. 52 Issue 40, p14319-14323, 5p |
| مصطلحات موضوعية: |
CATALYTIC activity, LEWIS acids, RING formation (Chemistry) |
| مستخلص: |
A general approach to prepare superhydrophobic MOFs (denoted as MOFs-CF3) through a post-decorating strategy for highly efficient chemical fixation of CO2 was demonstrated. The enhanced catalytic activity of MOFs-CF3 is attributed to a synergistic effect between the Lewis acid sites of MOFs and modification of the electron-withdrawing trifluoromethyl group, which resulted in a high CO2 enrichment capacity. The possible mechanism of cycloaddition catalyzed by the MOFs-CF3 catalyst was also proposed. [ABSTRACT FROM AUTHOR] |
|
Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) |
| قاعدة البيانات: |
Complementary Index |
