دورية أكاديمية

Strontium isotope compositions of Late Permian evaporites from the northernmost Thuringian Basin (Germany) indicate continental influence on the marine Zechstein Sea.

التفاصيل البيبلوغرافية
العنوان: Strontium isotope compositions of Late Permian evaporites from the northernmost Thuringian Basin (Germany) indicate continental influence on the marine Zechstein Sea.
المؤلفون: Käßner, A., Tichomirowa, M., Tandler, R., Ziebell, J.
المصدر: International Journal of Earth Sciences; Feb2024, Vol. 113 Issue 1, p49-63, 15p
مصطلحات موضوعية: STRONTIUM isotopes, GEOLOGICAL time scales, EVAPORITES, DRILL cores, SEAWATER, STRONTIUM ions, CHEMICAL weathering
مصطلحات جغرافية: EUROPE
مستخلص: In the Late Permian Zechstein Sea of Central Europe, up to 2000 m of evaporitic rocks were deposited in at least four consecutive cycles. The age of these evaporitic rocks could not yet be precisely determined, because they are virtually fossil-free and do not contain radiometrically datable volcanic layers. A chemostratigraphic age of the succession can be determined by comparing 87Sr/86Sr ratios of marine gypsum and anhydrite to the worldwide marine strontium evolution curve. Unfortunately, published 87Sr/86Sr data of the Zechstein succession are characterized by frequent outliers towards higher ratios, making an age assignment challenging. The scatter in 87Sr/86Sr ratios might be induced by different processes like the contribution of meteoric water to the brine, in-situ Rb decay, or post-depositional hydrothermal or diagenetic overprint. Here, we present a dataset of 26 new gypsum and anhydrite 87Sr/86Sr ratios from drill cores situated at "Alter Stolberg" in the northernmost Thuringian Basin. Evaporites of the Werra-, Staßfurt-, and Leine cycles were sampled. The close proximity of the drillings allows a very accurate assignment of the stratigraphic position of each sample, so that trends and outliers in 87Sr/86Sr ratios can easily be recognized. While the entire Werra Formation obviously revealed non-marine 87Sr/86Sr ratios, the lowermost 87Sr/86Sr ratios in the Staßfurt and Leine Formations can be assumed to represent marine ratios and allow estimating a chemostratigraphic age of 257‒254 Ma. The combination of the 87Sr/86Sr data with the mineral composition of the samples suggests a contribution of meteoric water, probably river water, to the Zechstein Sea as the main reason for the observed increase in 87Sr/86Sr ratios. Additional in-situ Rb decay, related to the riverine input of clay minerals, cannot be excluded. Modelling the amounts of sea water and meteoric water in the brine indicates that 83‒99% of meteoric water would be necessary to explain the highest 87Sr/86Sr ratios observed in the Werra Formation. [ABSTRACT FROM AUTHOR]
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قاعدة البيانات: Complementary Index
الوصف
تدمد:14373254
DOI:10.1007/s00531-023-02365-8