دورية أكاديمية

Thermo‐Kinetic Study of Piperazine Immobilized Silica Surface.

التفاصيل البيبلوغرافية
العنوان: Thermo‐Kinetic Study of Piperazine Immobilized Silica Surface.
المؤلفون: Sing, Varun Kumar, Sur, Souvik, Musharraf, Mohd., Dey, Ratan Kumar, Swain, Sanjay Kumar, Shekhar, Suman
المصدر: Macromolecular Symposia; Feb2024, Vol. 413 Issue 1, p1-7, 7p
مصطلحات موضوعية: PIPERAZINE, SILICA gel, ACTIVATION energy, SILICA
مستخلص: In the present study, the degradation process of piperazine (PP) immobilized silica gel (SiPP) is investigated under dynamic conditions. The degradation of SiPP is studied with thermogravimetric analyzer (TGA). The kinetics of degradation process is analyzed by Kissinger method, Flynn–Wall–Ozawa's (FWO) method, and Deconvolution method. It is found that degradation of SiPP can be described by parallel independent two‐portion process model, which includes two processing state of the system (marked by processes 1 and 2), where process 1 and 2 can be attributed to decomposition processes of organic moiety attached on silica surface. The apparent activation energy (Ea) is calculated by Flynn–Wall–Ozawa's (FWO) method and deconvolution method. [ABSTRACT FROM AUTHOR]
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قاعدة البيانات: Complementary Index
الوصف
تدمد:10221360
DOI:10.1002/masy.202300045