التفاصيل البيبلوغرافية
| العنوان: |
Synthesis of biheteroaryls via 2-methyl quinoline C(sp³)-H functionalization under metal-free conditions. |
| المؤلفون: |
Dahan Wang, Yuhan Yang, Fuhong Xiao, Jinbing Liu, Guojiang Mao, Guo-Jun Deng |
| المصدر: |
Green Synthesis & Catalysis; Feb2024, Vol. 5 Issue 1, p73-76, 4p |
| مصطلحات موضوعية: |
QUINOLINE, FUNCTIONAL groups, ESTERS, CHEMICAL reactions, ISOTHIAZOLE |
| مستخلص: |
An acetic acid-promoted C(sp³)-H functionalization of 2-methyl quinoline, enaminoesters and elemental sulfur for the synthesis of 3,4,5-trisubstituted isothiazoles under metal-free conditions has been developed. This approach provides viable access to various 5-(quinolin-2-yl)isothiazoles in moderate to good yields with good functional group tolerance. Moreover, the success of the gram-scale reaction gives this reaction a great potential application. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: |
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