دورية أكاديمية

Effects of rare earth ions on structural, morphological and photoluminescent properties of non-stoichiometric LiNbO3.

التفاصيل البيبلوغرافية
العنوان: Effects of rare earth ions on structural, morphological and photoluminescent properties of non-stoichiometric LiNbO3.
المؤلفون: Lovisa, L. X., Nunes, T. B. O., Tavares, E. C., Machado, R. C. L., Dos Santos, L. F., Bomio, M. R. D., Motta, F. V.
المصدر: Applied Physics A: Materials Science & Processing; Apr2024, Vol. 130 Issue 4, p1-15, 15p
مستخلص: The pseudo-ilmenite structure ABO3 have been increasingly highlighted in the optoelectronic area. Nanoparticles of undoped lithium niobates (LiNbO3) and codoped with rare earths (LiNbO3: Dy3+/Tb3+) were synthesized by the solid-state reaction method and calcined in a controlled way. The properties and structural changes of niobates were evaluated from data obtained in XRD and Rietveld refinement. The SEM-FEG micrographs showed different morphologies obtained (cubes, plates, tetrahedrons and polyhedra) according to the variation of the doping and co-doping process. Optical properties were measured and studied based on the results obtained from the UV-Vis spectrophotometer and photoluminescence assays. The photoluminescence presented by LiNbO3 was associated with the existence of superficial defects in the particles, i.e., centers of recombination of photogenerated charges favorable to the property. The effect of concentration of dopants was investigated in properties photoluminescence. Photometric measurements (CRI, purity, CCT, LER) were analyzed and a modulation of the emitted color as a function of the concentration of the dopants. According to the obtained results, LiNbO3: Dy3+/Tb3+ presents itself as a material with great potential in optical device applications. [ABSTRACT FROM AUTHOR]
Copyright of Applied Physics A: Materials Science & Processing is the property of Springer Nature and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
قاعدة البيانات: Complementary Index
الوصف
تدمد:09478396
DOI:10.1007/s00339-024-07399-6