التفاصيل البيبلوغرافية
| العنوان: |
Unlocking single molecule magnetism: a supramolecular strategy for isolating neutral MnIII salen-type dimer in crystalline environments? |
| المؤلفون: |
Yuri Kyoya, Kiyonori Takahashi, Wataru Kosaka, Rui-Kang Huang, Chen Xue, Jia-bing Wu, Hitoshi Miyasaka, Takayoshi Nakamura |
| المصدر: |
Dalton Transactions: An International Journal of Inorganic Chemistry; 5/7/2024, Vol. 53 Issue 17, p7517-7521, 5p |
| مصطلحات موضوعية: |
SINGLE molecules, SINGLE molecule magnets, MAGNETISM, DIMERS, MANGANESE porphyrins, CRYSTALS |
| مستخلص: |
In [Mn(5-MeOsalen)(Cl)]2(dibenzo[24]crown-8), dibenzo[24]crown-8 formed a supramolecule via multipoint interactions with the [Mn(5-MeOsalen)(Cl)] dimer. The dimer was magnetically isolated with ST = 4 and weak interdimer magnetic interactions. The crystal exhibited single-molecule magnet behaviour with an anisotropic barrier of 26(1) K, which is the highest among the Mn-salen series reported to date. [ABSTRACT FROM AUTHOR] |
|
Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) |
| قاعدة البيانات: |
Complementary Index |
