دورية أكاديمية
Dibenzoazepine hydrazine is a building block for N-alkene hybrid ligands: exploratory syntheses of complexes of Cu, Fe, and Li.
| العنوان: | Dibenzoazepine hydrazine is a building block for N-alkene hybrid ligands: exploratory syntheses of complexes of Cu, Fe, and Li. |
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| المؤلفون: | Grasruck, Alexander, Schall, Kristina, Heinemann, Frank W., Langer, Jens, Herrera, Alberto, Frieß, Sybille, Schmid, Günter, Dorta, Romano |
| المصدر: | Dalton Transactions: An International Journal of Inorganic Chemistry; 5/28/2024, Vol. 53 Issue 20, p8642-8656, 15p |
| مصطلحات موضوعية: | COPPER, HYDRAZINES, ALKENES, HYDRAZINE, PROTON transfer reactions, ELECTROPHILES |
| مستخلص: | The new hydrazine 5H-dibenzo[b,f]azepin-5-amine (2) reacts with P- and Si-electrophiles via deprotonation to afford P(III)-, P(V)-, and TMS-hydrazides 3–8 and with carbonyl electrophiles via acid-free condensation to the N-substituted hydrazones 9–12 that are potential N-alkene ligands. While β-ketohydrazone 9 and α-dihydrazone 10 react with [Mes(Cu)] |
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| قاعدة البيانات: | Complementary Index |
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