دورية أكاديمية
3‐Amido‐benzo[b]silines: Straightforward Modular 2‐Step Synthesis and Photophysical Properties.
| العنوان: | 3‐Amido‐benzo[b]silines: Straightforward Modular 2‐Step Synthesis and Photophysical Properties. |
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| المؤلفون: | Golling, Stéphane, Yan, Tianhong, Mazan, Valérie, Leroux, Frédéric R., Ciofini, Ilaria, Donnard, Morgan |
| المصدر: | Advanced Synthesis & Catalysis; 5/28/2024, Vol. 366 Issue 10, p2324-2333, 10p |
| مصطلحات موضوعية: | YNAMIDES, FLUORESCENCE, RING formation (Chemistry), DEHYDRATION, MANUSCRIPTS |
| مستخلص: | In this manuscript we report the synthesis of 3‐amido‐benzo[b]silines thanks to a 2‐step strategy involving a 3‐component silylformylation of ynamides followed by a Friedel‐Crafts cyclization/isomerizing dehydration domino sequence. This reaction is tolerant to various structural variations and has allowed us to synthesize a library of diversely substituted silacycles with yields from 33 to 85%. We also studied the fluorescence properties of these compounds which show structural similarities with recognized probes such as Si‐Rhodamine for example. [ABSTRACT FROM AUTHOR] |
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| قاعدة البيانات: | Complementary Index |
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