دورية أكاديمية

Ti--Si Mixed Oxides by Non-hydrolytic Sol--Gel Synthesis as Potential Gold Catalyst Supports for Gas-phase Epoxidation of Propylene in H2 and O2.

التفاصيل البيبلوغرافية
العنوان: Ti--Si Mixed Oxides by Non-hydrolytic Sol--Gel Synthesis as Potential Gold Catalyst Supports for Gas-phase Epoxidation of Propylene in H2 and O2.
المؤلفون: Maohua Dai, Dingliang Tang, Zhijie Lin, Hongwei Yang, Youzhu Yuan
المصدر: Chemistry Letters; 8/5/2006, Vol. 35 Issue 8, p24-24, 1p
مصطلحات موضوعية: OXIDES, TITANIUM, SILICON, PROPENE, GOLD
مستخلص: The amorphous Ti--Si mixed oxides prepared from chloride precursors using a one-step nonhydrolytic sol--gel route could serve as efficient gold catalyst supports for gas-phase epoxidation of propylene in O2 and H2. A propylene conversion of 6.8% at the initial 60 min and 4.0% after 4 h of time-on-steam, keeping a selectivity to propylene oxide as high as 95%, was obtained over the gold supported on a Ti--Si mixed oxide containing 10 mol % of Ti. [ABSTRACT FROM AUTHOR]
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قاعدة البيانات: Supplemental Index
الوصف
تدمد:03667022
DOI:10.1246/cl.2006.878