New Azo Chromophore-Containing Conjugated Polymers: Facile Synthesis by Using 'Click' Chemistry and Enhanced Nonlinear Optical Properties Through the Introduction of Suitable Isolation Groups
العنوان: | New Azo Chromophore-Containing Conjugated Polymers: Facile Synthesis by Using 'Click' Chemistry and Enhanced Nonlinear Optical Properties Through the Introduction of Suitable Isolation Groups |
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المؤلفون: | Cheng Ye, Jingui Qin, Zhong'an Li, Gui Yu, Zhen Li, Qi Zeng, Yunqi Liu |
المصدر: | Macromolecular Rapid Communications. 29:136-141 |
بيانات النشر: | Wiley, 2008. |
سنة النشر: | 2008 |
مصطلحات موضوعية: | chemistry.chemical_classification, Azo compound, Polymers and Plastics, Chemistry, Organic Chemistry, Second-harmonic generation, Nonlinear optics, Polymer, Conjugated system, Chromophore, Combinatorial chemistry, chemistry.chemical_compound, Polymer chemistry, Materials Chemistry, Click chemistry, Thermal stability |
الوصف: | A new series of azobenzene-containing polyfluorenes have been successfully prepared through polymer reactions by the utilization of "click" chemistry. All the polymers were well characterized and soluble in common solvents. By the application of the concept of "suitable isolation group", the macroscopic nonlinear optical (NLO) properties of the polymers could be boosted to as large as three times that of the polymer without isolation moieties. Also, all the polymers were thermally stable, and demonstrated good procesability, coupled with improved optical transparency. Thus, they are good candidates for the practical applications as new photonic materials. |
تدمد: | 1521-3927 1022-1336 |
URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::14da931e9535e6f430e09f5d3174704d https://doi.org/10.1002/marc.200700599 |
حقوق: | CLOSED |
رقم الأكسشن: | edsair.doi...........14da931e9535e6f430e09f5d3174704d |
قاعدة البيانات: | OpenAIRE |
تدمد: | 15213927 10221336 |
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