Kinetics and Transport at AMTEC Electrodes: I . The Interfacial Impedance Model
العنوان: | Kinetics and Transport at AMTEC Electrodes: I . The Interfacial Impedance Model |
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المؤلفون: | Barbara Jeffries-Nakamura, Roger M. Williams, J. T. Kummer, C. P. Bankston, M. E. Loveland, M. L. Underwood, H. Leduc |
المصدر: | Journal of The Electrochemical Society. 137:1709-1716 |
بيانات النشر: | The Electrochemical Society, 1990. |
سنة النشر: | 1990 |
مصطلحات موضوعية: | Renewable Energy, Sustainability and the Environment, Chemistry, Sodium, Inorganic chemistry, chemistry.chemical_element, Alkali-metal thermal to electric converter, Electrolyte, Condensed Matter Physics, Electrochemistry, Alkali metal, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, Electrochemical cell, Chemical engineering, Electrode, Materials Chemistry, Ionic conductivity |
الوصف: | Mixed mass-transport and kinetic control of sodium ion reduction at porous inert electrodes on sodium beta-double-prime alumina solid electrolyte (BASE) ceramic in a high-temperature electrochemical cell has been observed and modeled. The high ionic conductivity of BASE and the reversibility of the liquid sodium/BASE anodic half-cell led to assignment of potential-dependent (nonohmic) resistances to kinetic and mass-transport processes associated with the porous electrode. The morphology of these electrodes and typical sodium gas pressures are consistent with Knudsen, or free-molecular, flow through the electrode. |
تدمد: | 1945-7111 0013-4651 |
URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::35a543684ea81aecc2dc71197c8bfd25 https://doi.org/10.1149/1.2086775 |
حقوق: | CLOSED |
رقم الأكسشن: | edsair.doi...........35a543684ea81aecc2dc71197c8bfd25 |
قاعدة البيانات: | OpenAIRE |
تدمد: | 19457111 00134651 |
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