Kinetics and Transport at AMTEC Electrodes: I . The Interfacial Impedance Model

التفاصيل البيبلوغرافية
العنوان: Kinetics and Transport at AMTEC Electrodes: I . The Interfacial Impedance Model
المؤلفون: Barbara Jeffries-Nakamura, Roger M. Williams, J. T. Kummer, C. P. Bankston, M. E. Loveland, M. L. Underwood, H. Leduc
المصدر: Journal of The Electrochemical Society. 137:1709-1716
بيانات النشر: The Electrochemical Society, 1990.
سنة النشر: 1990
مصطلحات موضوعية: Renewable Energy, Sustainability and the Environment, Chemistry, Sodium, Inorganic chemistry, chemistry.chemical_element, Alkali-metal thermal to electric converter, Electrolyte, Condensed Matter Physics, Electrochemistry, Alkali metal, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials, Electrochemical cell, Chemical engineering, Electrode, Materials Chemistry, Ionic conductivity
الوصف: Mixed mass-transport and kinetic control of sodium ion reduction at porous inert electrodes on sodium beta-double-prime alumina solid electrolyte (BASE) ceramic in a high-temperature electrochemical cell has been observed and modeled. The high ionic conductivity of BASE and the reversibility of the liquid sodium/BASE anodic half-cell led to assignment of potential-dependent (nonohmic) resistances to kinetic and mass-transport processes associated with the porous electrode. The morphology of these electrodes and typical sodium gas pressures are consistent with Knudsen, or free-molecular, flow through the electrode.
تدمد: 1945-7111
0013-4651
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::35a543684ea81aecc2dc71197c8bfd25
https://doi.org/10.1149/1.2086775
حقوق: CLOSED
رقم الأكسشن: edsair.doi...........35a543684ea81aecc2dc71197c8bfd25
قاعدة البيانات: OpenAIRE