Philippine natural zeolite surface engineered with CuO nanowires via a one-step thermal decomposition route

التفاصيل البيبلوغرافية
العنوان: Philippine natural zeolite surface engineered with CuO nanowires via a one-step thermal decomposition route
المؤلفون: Hideki Nakajima, Herman D. Mendoza, Eleanor M. Olegario, Christian Mark Pelicano, Jenichi Clairvaux Felizco
المصدر: Journal of the Australian Ceramic Society. 56:803-809
بيانات النشر: Springer Science and Business Media LLC, 2019.
سنة النشر: 2019
مصطلحات موضوعية: 010302 applied physics, Materials science, Annealing (metallurgy), Composite number, Thermal decomposition, Nanowire, 02 engineering and technology, 021001 nanoscience & nanotechnology, 01 natural sciences, Catalysis, Chemical engineering, X-ray photoelectron spectroscopy, 0103 physical sciences, 0210 nano-technology, Zeolite, Porosity
الوصف: Novel CuO nanowire-zeolite composite was successfully fabricated through facile thermal decomposition of CuSO4 • 5H2O as the lone precursor. The natural zeolites have porous and plate-like structures, which suggest the presence of clinoptilolite-heulandite family of zeolites. After annealing of Cu-exchanged zeolite at 550 °C, CuO nanowires were synthesized with a mean diameter of 80 nm and length of 1.5 μm. XRD analysis revealed that the samples annealed at 550 °C showed clinoptilolite-heulandite peaks, as well as a broad CuO peak. Annealing at a higher temperature of 800 °C led to the amorphization of the zeolite peaks. The XPS spectra of the zeolite with Cu annealed at 400, 550, and 800 °C confirmed that annealing at 550 °C preferably forms CuO rather than Cu2O on zeolite surface. These analyses identified that annealing at 550 °C functionalized the Cu-exchanged zeolite surface, which is desirable for a wide variety of applications such as catalysis, sorbents for environmental applications, and gas sensors.
تدمد: 2510-1579
2510-1560
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::50e668e3954fc41356576d7cb3b86c17
https://doi.org/10.1007/s41779-019-00401-y
حقوق: CLOSED
رقم الأكسشن: edsair.doi...........50e668e3954fc41356576d7cb3b86c17
قاعدة البيانات: OpenAIRE