Philippine natural zeolite surface engineered with CuO nanowires via a one-step thermal decomposition route
العنوان: | Philippine natural zeolite surface engineered with CuO nanowires via a one-step thermal decomposition route |
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المؤلفون: | Hideki Nakajima, Herman D. Mendoza, Eleanor M. Olegario, Christian Mark Pelicano, Jenichi Clairvaux Felizco |
المصدر: | Journal of the Australian Ceramic Society. 56:803-809 |
بيانات النشر: | Springer Science and Business Media LLC, 2019. |
سنة النشر: | 2019 |
مصطلحات موضوعية: | 010302 applied physics, Materials science, Annealing (metallurgy), Composite number, Thermal decomposition, Nanowire, 02 engineering and technology, 021001 nanoscience & nanotechnology, 01 natural sciences, Catalysis, Chemical engineering, X-ray photoelectron spectroscopy, 0103 physical sciences, 0210 nano-technology, Zeolite, Porosity |
الوصف: | Novel CuO nanowire-zeolite composite was successfully fabricated through facile thermal decomposition of CuSO4 • 5H2O as the lone precursor. The natural zeolites have porous and plate-like structures, which suggest the presence of clinoptilolite-heulandite family of zeolites. After annealing of Cu-exchanged zeolite at 550 °C, CuO nanowires were synthesized with a mean diameter of 80 nm and length of 1.5 μm. XRD analysis revealed that the samples annealed at 550 °C showed clinoptilolite-heulandite peaks, as well as a broad CuO peak. Annealing at a higher temperature of 800 °C led to the amorphization of the zeolite peaks. The XPS spectra of the zeolite with Cu annealed at 400, 550, and 800 °C confirmed that annealing at 550 °C preferably forms CuO rather than Cu2O on zeolite surface. These analyses identified that annealing at 550 °C functionalized the Cu-exchanged zeolite surface, which is desirable for a wide variety of applications such as catalysis, sorbents for environmental applications, and gas sensors. |
تدمد: | 2510-1579 2510-1560 |
URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::50e668e3954fc41356576d7cb3b86c17 https://doi.org/10.1007/s41779-019-00401-y |
حقوق: | CLOSED |
رقم الأكسشن: | edsair.doi...........50e668e3954fc41356576d7cb3b86c17 |
قاعدة البيانات: | OpenAIRE |
تدمد: | 25101579 25101560 |
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