Dual-Emissive Langmuir–Blodgett Films of a 9,9-Bis(4-ethynylphenyl)fluorene Derivative of Gold(I) and Some Europium-Substituted Polyoxometalates: Preparation, Characterization and Photoelectric Properties
| العنوان: | Dual-Emissive Langmuir–Blodgett Films of a 9,9-Bis(4-ethynylphenyl)fluorene Derivative of Gold(I) and Some Europium-Substituted Polyoxometalates: Preparation, Characterization and Photoelectric Properties |
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| المؤلفون: | Zu Liang Du, Wai Yeung Wong, Li Liu, Hui Fu, Lei Hu, Qiao Min Fu, Shi Zhong Liu |
| المصدر: | Journal of Inorganic and Organometallic Polymers and Materials. 22:97-104 |
| بيانات النشر: | Springer Science and Business Media LLC, 2011. |
| سنة النشر: | 2011 |
| مصطلحات موضوعية: | Materials science, Photoluminescence, Polymers and Plastics, chemistry.chemical_element, Fluorene, Langmuir–Blodgett film, law.invention, chemistry.chemical_compound, chemistry, law, Polyoxometalate, Materials Chemistry, Organic chemistry, Molecule, Physical chemistry, Scanning tunneling microscope, Europium, Spectroscopy |
| الوصف: | A new family of organometallic/inorganic composite Langmuir–Blodgett (LB) films consisting of the rigid-rod dinuclear gold(I) complex coordinated with 9,9-bis(4-ethynylphenyl)fluorene (denoted as Au-DPF) as the π-conjugated organometallic molecule coupled with some europium-substituted polyoxometalates (POM; POM = Na9EuW10O36, K13[Eu(SiW11O39)2] and K5[Eu(SiW11O39)(H2O)2]) as the inorganic component were prepared and characterized by π–A isotherms, UV–vis absorption and photoluminescence spectra, atomic force microscopy imaging, scanning tunneling microscopy, and surface photo-voltage spectroscopy. Luminescence spectra of the prepared hybrid LB films show that the near-white emission spectra can be obtained due to the dual-emissive nature of the mixed Au-DPF/POM blends, and POM can facilitate broad aggregate emission bands. These Au-diyne-based LB films displayed interesting electric conductivity behavior. Among them, Au-DPF/K13[Eu(SiW11O39)2] 13-layer film showed a good electrical response, with the tunneling current up to ±100 nA when the voltage was monitored between −1.3 and 1.8 V. The photovoltage response of Au-DPF/EuW22 amounts to 1.5 μV. |
| تدمد: | 1574-1451 1574-1443 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::7c962e40fd4074fda26c7f56395fb040 https://doi.org/10.1007/s10904-011-9579-2 |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi...........7c962e40fd4074fda26c7f56395fb040 |
| قاعدة البيانات: | OpenAIRE |
Find this article in full text from Springer Verlag. | تدمد: | 15741451 15741443 |
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