A new catalytic hybrid material from simple acid–base hydrolytic chemistry
العنوان: | A new catalytic hybrid material from simple acid–base hydrolytic chemistry |
---|---|
المؤلفون: | David Fenwick, Ashok K. Kakkar, Maria G. L. Petrucci |
المصدر: | Journal of Molecular Catalysis A: Chemical. 146:309-315 |
بيانات النشر: | Elsevier BV, 1999. |
سنة النشر: | 1999 |
مصطلحات موضوعية: | Process Chemistry and Technology, Dimer, Silane, Catalysis, chemistry.chemical_compound, Hydrolysis, chemistry, Organic chemistry, Bibenzyl, Physical and Theoretical Chemistry, Hybrid material, Diphenylacetylene, Phosphine |
الوصف: | The synthesis of a new inorganic–organic hybrid material in a non-aqueous medium from acid–base hydrolysis of octadecyltri(amino)silane with tri(hydroxypropyl)phosphine, is reported. Rh(I) metal centers are easily introduced into the network by reacting it with the dimer, [Rh(μ-Cl)(1,5-C 8 H 12 )] 2 , and the resulting organometallic–inorganic hybrid shows preference for the fully hydrogenated product (bibenzyl) in the catalytic hydrogenation of diphenylacetylene. |
تدمد: | 1381-1169 |
URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::b30d3c4bb1ba071358398f26488f9888 https://doi.org/10.1016/s1381-1169(99)00090-4 |
حقوق: | CLOSED |
رقم الأكسشن: | edsair.doi...........b30d3c4bb1ba071358398f26488f9888 |
قاعدة البيانات: | OpenAIRE |
كن أول من يترك تعليقا!