Characterization of hybrid copolymer containing thermosensitive and polypeptide blocks by thermogravimetric analysis
| العنوان: | Characterization of hybrid copolymer containing thermosensitive and polypeptide blocks by thermogravimetric analysis |
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| المؤلفون: | Sevdalina Turmanova, Ivaylo Dimitrov, Velyana G. Georgieva, Emilya D. Ivanova |
| المصدر: | Polymer Bulletin. 71:167-179 |
| بيانات النشر: | Springer Science and Business Media LLC, 2013. |
| سنة النشر: | 2013 |
| مصطلحات موضوعية: | Work (thermodynamics), Thermogravimetric analysis, Materials science, Polymers and Plastics, Activated complex, Kinetics, chemistry.chemical_element, General Chemistry, Condensed Matter Physics, Kinetic energy, Nitrogen, chemistry, Reagent, Polymer chemistry, Materials Chemistry, Copolymer, Physical chemistry |
| الوصف: | Thermogravimetric studies of polypeptide-based hybrid copolymer (PNIPAm-g-PEG)-b-PLys in a flow of nitrogen were carried out at four rates of linear increase of the temperature. The kinetics and mechanism of the degradation process were evaluated from the TG data using the iso-conversional calculation procedure of Kissinger–Akahira–Sunose recommended by the ICTAC kinetics committee. It is very important to determine the most probable function of the mechanism, because the kinetic parameters of the process depend on its selection. In this respect, the iso-conversion calculation procedure turned out to be the most appropriate one. In the present work, the kinetic triplet (E, A and the shape of the most appropriate f(α)-function) of this process, as well as the kinetic parameters for the formation of the activated complex from the reagent, was calculated. All the calculations were performed using programs developed by us. |
| تدمد: | 1436-2449 0170-0839 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::cc8bc7004bfbdafd66bfdf93599c566b https://doi.org/10.1007/s00289-013-1052-7 |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi...........cc8bc7004bfbdafd66bfdf93599c566b |
| قاعدة البيانات: | OpenAIRE |
Find this article in full text from Springer Verlag. | تدمد: | 14362449 01700839 |
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