Interconnected CoS2/NC-CNTs network as high-performance anode materials for lithium-ion batteries

التفاصيل البيبلوغرافية
العنوان: Interconnected CoS2/NC-CNTs network as high-performance anode materials for lithium-ion batteries
المؤلفون: Lingjun Kong, Wei Xu, Hui Huang, Ming Liu, Baiyan Li, Xian-He Bu, Yingying Liu
المصدر: Science China Materials. 64:820-829
بيانات النشر: Springer Science and Business Media LLC, 2020.
سنة النشر: 2020
مصطلحات موضوعية: Battery (electricity), Materials science, Nanostructure, chemistry.chemical_element, Nanoparticle, Nanotechnology, 02 engineering and technology, Carbon nanotube, 010402 general chemistry, 021001 nanoscience & nanotechnology, 01 natural sciences, 0104 chemical sciences, law.invention, Anode, chemistry, law, Electrode, General Materials Science, Lithium, 0210 nano-technology, Carbon
الوصف: Cobalt disulfide (CoS2) has been considered a promising anode material for lithium-ion batteries (LIBs) due to its high theoretical capacity of 870 mA h g−1. However, its practical applications have been hampered by undesirable cycle life and rate performance due to the volume change and deterioration of electronic conductivity during the discharge-charge process. In this study, an interconnected CoS2/N-doped carbon/carbon nanotube (CoS2/NC-CNTs-700) network was successfully prepared to boost its lithium storage performance, in which small-size CoS2 nanoparticles were confined by N-doped carbon and uniformly decorated on the surface of CNTs. N-doped carbon can effectively accommodate the large volume expansion of CoS2 nanoparticles. Additionally, the 3D conductive nanostructure design offers adequate electrical/mass transport spacing. Benefiting from this, the CoS2/NC-CNTs-700 electrode demonstrates a long cycle life (a residual capacity of 719 mA h g−1 after 100 cycles at 0.2 A g−1) and outstanding rate performance (335 mA h g−1 at 5.0 A g−1). This study broadens the design and application of CoS2 and fosters the advances in battery anode research.
تدمد: 2199-4501
2095-8226
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_________::e6fec4815d111f80aa933611413e5428
https://doi.org/10.1007/s40843-020-1477-0
حقوق: OPEN
رقم الأكسشن: edsair.doi...........e6fec4815d111f80aa933611413e5428
قاعدة البيانات: OpenAIRE