Bridged and fused triazolic energetic frameworks with an azo building block towards thermally stable and applicable propellant ingredients
| العنوان: | Bridged and fused triazolic energetic frameworks with an azo building block towards thermally stable and applicable propellant ingredients |
|---|---|
| المؤلفون: | Jean'ne M. Shreeve, Feng-sheng Li, Ping Yin, Siping Pang, Richard J. Staples, Qiong Yu |
| المصدر: | Journal of Materials Chemistry A. 9:24903-24908 |
| بيانات النشر: | Royal Society of Chemistry (RSC), 2021. |
| سنة النشر: | 2021 |
| مصطلحات موضوعية: | Propellant, Materials science, Renewable Energy, Sustainability and the Environment, Thermal decomposition, Detonation, General Chemistry, Ammonium perchlorate, Energetic material, Combinatorial chemistry, Oxygen balance, chemistry.chemical_compound, chemistry, Molecule, General Materials Science, Thermal stability |
| الوصف: | The assembly of nitrogen-rich building blocks determines the energy storage capacity and affects the stability of energetic materials. Owing to the environmentally harmful properties of the propellant, ammonium perchlorate (AP), much research has explored halogen-free replacements which often suffer from poor thermal stability. In our goal of balancing performance and stability, we report access to an energetic molecule (3) by smart assembly of an azo bridge into trinitromethyl triazoles. Compound 3 exhibits a decomposition temperature of 175 °C, which approaches the highest among reported trinitromethyl derivatives. The density (1.91 g cm−3) and oxygen balance (+29%) for 3 exceed other candidates, suggesting it as a high energy dense oxidizer (HEDO) replacement for AP in rocket propellants. One-step azo-involved cyclization of 3 give two fused nitro triazolones, (FNTO) 4 and its N-oxide 5, having thermal stabilities and energies superior to the analogous derivatives of 5-nitro-2,4-dihydro-3H-1,2,4-triazole-3-one (NTO). The comparison of properties of the fused triazolones 4 and 8 and their N-oxide derivatives 5 and 9 shows that formation of an N-oxide is an effective strategy which results in an increase of the decomposition temperature, oxygen balance, specific impulse, and detonation properties and in a decrease of the sensitivity of the corresponding energetic material. This work highlights bridged and fused triazolic energetic frameworks with an azo building block providing an alternative structural motif for seeking an applicable high-energy ingredient. |
| تدمد: | 2050-7496 2050-7488 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_________::ef9d5cd5281dcf7764f2fb74948c55ba https://doi.org/10.1039/d1ta07520a |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi...........ef9d5cd5281dcf7764f2fb74948c55ba |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 20507496 20507488 |
|---|