Hydrogen-terminated silicon nanoparticles (H-SiNPs) inhibit anerobic thermal autopolymerization of methacrylates. When heated to 100 °C under an inert atmosphere, allyl methacrylate (AMA) was stable for at least 95 h in the presence of 1.2 wt % H-SiNPs, exhibiting less than 0.15% conversion, whereas the neat monomer solidified within 24 h (over 10% conversion after 34 h). A mechanism is proposed that is based on H-transfer from SiNPs to the thermally activated methacrylic dimer biradical, quenching autopolymerization. An analysis of SiNPs isolated after heating in AMA reveals the grafting of ester groups. Thermal hydrosilylation offers a facile way to attach an allyl group to the surface of SiNPs.
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