Photoinduced arylation of chloroarenes in flow: synthesis of unsymmetrical biaryls
| العنوان: | Photoinduced arylation of chloroarenes in flow: synthesis of unsymmetrical biaryls |
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| المؤلفون: | Zih-Siang Hong, Shih-Chieh Kao, Yu-Tsen Cheng, Chun-Jen Chen, Yen-Ku Wu |
| المصدر: | Organic & Biomolecular Chemistry. 20:8212-8216 |
| بيانات النشر: | Royal Society of Chemistry (RSC), 2022. |
| سنة النشر: | 2022 |
| مصطلحات موضوعية: | Bromides, Chlorides, Organic Chemistry, Iodides, Physical and Theoretical Chemistry, Biochemistry, Catalysis |
| الوصف: | A photoflow method is presented for a radical-based coupling of unactivated arenes and aryl chlorides. The process proceeded smoothly at ambient temperature under metal-free conditions. Of note is that the reaction conditions are fine-tuned for chloroarenes with different electronic properties. While the reactivity profile of aryl chlorides is generally known to be inferior to those of the corresponding iodides and bromides, we demonstrate that the title protocol is efficient in converting readily available and inexpensive chloroarenes into unsymmetrical biaryl products. |
| تدمد: | 1477-0539 1477-0520 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3877775ccf2f3ecf1bba2bc169107112 https://doi.org/10.1039/d2ob01710e |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi.dedup.....3877775ccf2f3ecf1bba2bc169107112 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 14770539 14770520 |
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