Synthesis and properties of some gelatin derivatives with substituents at the amino group
العنوان: | Synthesis and properties of some gelatin derivatives with substituents at the amino group |
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المؤلفون: | A. N. Pratt, R. T. Jones, R. C. Clark, D. A. Sutton, A. A. Leach, W. G. Cobbett, J. A. Gibbs |
المصدر: | Journal of Applied Chemistry. 15:479-488 |
بيانات النشر: | Wiley, 2007. |
سنة النشر: | 2007 |
مصطلحات موضوعية: | Reaction conditions, Coacervate, Aqueous solution, food.ingredient, Chemistry, Toxicology, Chloride, Gelatin, food, Phase (matter), medicine, Organic chemistry, Reactivity (chemistry), Solubility, medicine.drug |
الوصف: | Gelatin has been interacted with benzenesulphonyl chloride and with other sulphonyl chlorides to give sulphonyl-gelatin derivatives. With dichloro-s-triazines, gelatin afforded crosslinked products or monofunctionally substituted soluble products according to the reactivity of the dichloro-s-triazine selected and the reaction conditions used; some of the monofunctionally substituted soluble products were reactive towards amines, including gelatin. The properties of the modified gelatins are recorded. Introduction of a sufficient number of hydrophobic groups into gelatin and other soluble proteins conferred diminished solubility in the region of the iso-ionic point of the derivative, bringing about the separation of a distinct protein-rich phase (coacervate) from aqueous solution when the pH was adjusted to that region. Some uses of these derivatives are indicated. |
تدمد: | 1934-998X 0021-8871 |
URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::62bc2373239caa07bb8fa531d68edcbd https://doi.org/10.1002/jctb.5010151008 |
حقوق: | CLOSED |
رقم الأكسشن: | edsair.doi.dedup.....62bc2373239caa07bb8fa531d68edcbd |
قاعدة البيانات: | OpenAIRE |
تدمد: | 1934998X 00218871 |
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