EFFECT OF COEXISTING COMPOUNDS ON THE SORPTION AND REDUCTION OF TRICHLOROETHYLENE WITH IRON
العنوان: | EFFECT OF COEXISTING COMPOUNDS ON THE SORPTION AND REDUCTION OF TRICHLOROETHYLENE WITH IRON |
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المؤلفون: | Hyun-Hee Cho, Jae-Woo Park |
المصدر: | Environmental Toxicology and Chemistry. 24:11 |
بيانات النشر: | Wiley, 2005. |
سنة النشر: | 2005 |
مصطلحات موضوعية: | Nitrates, Iron filings, Passivation, Trichloroethylene, Chromate conversion coating, Iron, Health, Toxicology and Mutagenesis, Inorganic chemistry, Sorption, Naphthalenes, chemistry.chemical_compound, Models, Chemical, Nitrate, chemistry, Chromates, Carbon tetrachloride, Environmental Chemistry, Adsorption, Carbon Tetrachloride, Oxidation-Reduction, Naphthalene |
الوصف: | Batch experiments were performed to study the effect of coexisting compounds on trichloroethylene (TCE) dechlorination and sorption in the presence of iron. Competitive sorption of TCE was observed with naphthalene as a coexisting contaminant, but the TCE reduction rate slightly increased with naphthalene, which is hardly subject to reduction. With carbon tetrachloride, nitrate, and chromate as reducible cocontaminants, the competitive reduction of TCE was observed in binary-contaminant systems. The reduction rate constant of TCE by iron filings decreased 1.5 times with carbon tetrachloride because of the competition for electrons. The TCE reduction rate with nitrate decreased five times because of the competition for electrons and the enhanced passivation. The sorbed mass of TCE on iron surface with chromate increased more than that without chromate because of the formation of (Cr, Fe)(OH)3 precipitations. |
تدمد: | 1552-8618 0730-7268 |
URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6fef047c9e716615600ac8d4aa07af2b https://doi.org/10.1897/04-051r.1 |
حقوق: | CLOSED |
رقم الأكسشن: | edsair.doi.dedup.....6fef047c9e716615600ac8d4aa07af2b |
قاعدة البيانات: | OpenAIRE |
تدمد: | 15528618 07307268 |
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