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Preventing Anion Exchange between Perovskite Nanocrystals by Confinement in Porous SiO2 Nanobeads

التفاصيل البيبلوغرافية
العنوان: Preventing Anion Exchange between Perovskite Nanocrystals by Confinement in Porous SiO2 Nanobeads
المؤلفون: Zhenda Lu, Yucong Su, Xing Xing, Yue Xu, Qiang Jing
المصدر: ACS Omega, Vol 4, Iss 26, Pp 22209-22213 (2019)
ACS Omega
بيانات النشر: American Chemical Society, 2019.
سنة النشر: 2019
مصطلحات موضوعية: Fabrication, Materials science, Ion exchange, General Chemical Engineering, Halide, General Chemistry, Article, Ion, law.invention, Chemistry, Chemical engineering, Nanocrystal, law, Luminescence, QD1-999, Perovskite (structure), Light-emitting diode
الوصف: All-inorganic CsPbX3 (X = Cl, Br, I) perovskite nanocrystals (NCs) are highly attractive due to their outstanding optical and electrical properties. However, poor stability and easy anion exchanges between CsPbX3 nanocrystals with different halides limit their applications in light-emitting diodes (LEDs). To solve the problems, we developed an approach to in situ synthesize CsPbX3 NCs into porous silica colloidal spheres, which can effectively prevent anion exchange and increase photo stability. Based on our results, we first proved that the anion exchange between CsPbX3 nanocrystals is mainly driven by physical collision of the nanocrystals, not requiring a bridge such as a solvent. We subsequently used an optimized ratio of green, red, and blue SiO2/CsPbX3 composites as solid-state luminescent materials to fabricate single-layer white light-emitting diodes (WLEDs). No anion exchanges have been observed in the LED fabrication and lighting process.
اللغة: English
تدمد: 2470-1343
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9278b4692c46f3d383e816ffe27d6a1b
https://doaj.org/article/ab1d229898c04412a1a4d61b53389ca9
حقوق: OPEN
رقم الأكسشن: edsair.doi.dedup.....9278b4692c46f3d383e816ffe27d6a1b
قاعدة البيانات: OpenAIRE
الوصف
تدمد:24701343