Organic photoredox catalytic amino-heteroarylation of unactivated olefins to access distal amino ketones
| العنوان: | Organic photoredox catalytic amino-heteroarylation of unactivated olefins to access distal amino ketones |
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| المؤلفون: | Ji-Hua Zhang, Teng-Fei Xiao, Zi-Qin Ji, Han-Nan Chen, Pen-Ji Yan, Yong-Chun Luo, Peng-Fei Xu, Guo-Qiang Xu |
| المصدر: | Chemical Communications. 58:2882-2885 |
| بيانات النشر: | Royal Society of Chemistry (RSC), 2022. |
| سنة النشر: | 2022 |
| مصطلحات موضوعية: | Materials Chemistry, Metals and Alloys, Ceramics and Composites, General Chemistry, Catalysis, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials |
| الوصف: | A metal-free amino-heteroarylation of unactivated olefins via new organic photoredox catalysis was reported, providing a concise and efficient approach for the rapid synthesis of various δ (β, ε)-amino ketones under mild conditions. A series of mechanistic experiments and DFT calculations indicate that this transformation undergoes a photoredox catalytic sequential radical addition/functional group migration process. |
| تدمد: | 1364-548X 1359-7345 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ab42659874559405d4b5a074cdf9ae40 https://doi.org/10.1039/d1cc07189k |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi.dedup.....ab42659874559405d4b5a074cdf9ae40 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 1364548X 13597345 |
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