Branching ratios and absolute cross sections of dissociative recombination processes of N2O+

التفاصيل البيبلوغرافية
العنوان: Branching ratios and absolute cross sections of dissociative recombination processes of N2O+
المؤلفون: Anneli Ehlerding, F. Hellberg, Mats Larsson, Richard D. Thomas, A. Paál, Vitali Zhaunerchyk, Ansgar Simonsson, S. Rosén, M. af Ugglas, Magdalena Kaminska, Wolf D. Geppert, Mathias Hamberg, Anders Källberg
المصدر: Physical chemistry chemical physics : PCCP. 7(8)
سنة النشر: 2009
مصطلحات موضوعية: Kinetics, Branching fraction, Chemistry, Nitrous Oxide, General Physics and Astronomy, Thermodynamics, Physical and Theoretical Chemistry, Atomic physics, Branching (polymer chemistry), Dissociative recombination, Afterglow, Ion
الوصف: We have investigated the dissociative recombination of the N2O+ ion using the CRYRING heavy-ion storage ring at the Manne Siegbahn laboratory in Stockholm, Sweden. The dissociative recombination branching ratios were determined at minimal (approximately 0 eV) collision energy, showing that the dominating pathways involved two-body fragmentation: N2 + O (48%) and NO + N (36%). The branching ratio of the three-body break-up 2N + O was 16%. The overall thermal rate coefficient of the title reaction follows the expression k(T) = 3.34 +/- 0.75 x 10(-7) (T/300) (-0.57+/- 0.03 cm3 s(-1)), which correlates perfectly with earlier flowing afterglow studies on the same process.
تدمد: 1463-9076
URL الوصول: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::baddf8b65d1d0d621a4bc55968fc293d
https://pubmed.ncbi.nlm.nih.gov/19787922
رقم الأكسشن: edsair.doi.dedup.....baddf8b65d1d0d621a4bc55968fc293d
قاعدة البيانات: OpenAIRE