(Hetero)arene-fused boroles: a broad spectrum of applications
| العنوان: | (Hetero)arene-fused boroles: a broad spectrum of applications |
|---|---|
| المؤلفون: | Florian Rauch, Todd B. Marder, Jiang He, Maik Finze |
| المصدر: | Chemical Science |
| بيانات النشر: | Royal Society of Chemistry (RSC), 2021. |
| سنة النشر: | 2021 |
| مصطلحات موضوعية: | Chemistry, Broad spectrum, chemistry.chemical_compound, chemistry, Surface modification, chemistry.chemical_element, General Chemistry, Borole, Boron, Boron atom, Ring (chemistry), Combinatorial chemistry, Antiaromaticity |
| الوصف: | (Hetero)arene-fused boroles are a class of compounds containing a 5-membered boron diene-ring. Based on their molecular framework, the (hetero)arene-fused boroles can be considered as boron-doped polycyclic antiaromatic hydrocarbons and are thus of great interest. Due to the vacant pz orbital on the 3-coordinate boron atom, the antiaromaticity and strain of the 5-membered borole ring, (hetero)arene-fused boroles possess strong electron accepting abilities and Lewis acidity. By functionalization, they can be tuned to optimize different properties for specific applications. Herein, we summarize synthetic methodologies, different strategies for their functionalization, and applications of (hetero)arene-fused boroles. (Hetero)arene-fused boroles, ‘antiaromatic’ 2n-electron π-systems, more stable and more functionalizable than boroles, offer greater potential for a variety of applications. |
| تدمد: | 2041-6539 2041-6520 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bd8488e070a5761b325667f70b053b60 https://doi.org/10.1039/d0sc05676f |
| حقوق: | OPEN |
| رقم الأكسشن: | edsair.doi.dedup.....bd8488e070a5761b325667f70b053b60 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 20416539 20416520 |
|---|