Syntheses, structures and antimicrobial properties of complexes based on 2-hydroxybenzaldehyde-4-aminoantipyrine Schiff base
العنوان: | Syntheses, structures and antimicrobial properties of complexes based on 2-hydroxybenzaldehyde-4-aminoantipyrine Schiff base |
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المؤلفون: | Quan Tang, Jing Hu, Ming Xu, Xin-Cheng Yang, Wen-Ge Li, Yi-Jie Ding, Yi-Fan Zhang, Lili Liang, Hui-Fang Li |
المصدر: | Journal of Coordination Chemistry. 74:1039-1052 |
بيانات النشر: | Informa UK Limited, 2021. |
سنة النشر: | 2021 |
مصطلحات موضوعية: | Schiff base, Ligand, 2-hydroxybenzaldehyde, 010402 general chemistry, 010403 inorganic & nuclear chemistry, Antimicrobial, 01 natural sciences, 0104 chemical sciences, chemistry.chemical_compound, Monomer, chemistry, Polymer chemistry, Materials Chemistry, Physical and Theoretical Chemistry |
الوصف: | Two monomeric complexes, [NiL2·3H2O] (1) and [Nd2L3(NO3)3] (2), with a tridentate ONO-donor Schiff base ligand HL (HL = 2-hydroxybenzaldehyde-4-aminoantipyrine) have been synthesized. Single-crystal X-ray diffraction analysis indicates that the asymmetric unit of 1 contains one Ni(II) and two L− ligands, while 2 consists of two Nd(III) ions, three L− ligands, and three NO3− ions. Complexes 1 and 2 are both 0-D discrete monomers, and there are intermolecular π–π interactions in 1 and intramolecular π–π interactions in 2. The discrete [NiL2·3H2O] monomers are further connected through π–π interactions, resulting in a 3-D supramolecular structure. Powder XRD and TG-DSC were performed for 1 and 2. Antimicrobial experiments show that 1 displays significant antibacterial effect against Bacillary dysentery and Escherichia coli in comparison with that of Schiff base ligand. |
تدمد: | 1029-0389 0095-8972 |
URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cb7f060666e02e4a11b1bf3fd684ecb3 https://doi.org/10.1080/00958972.2021.1875449 |
حقوق: | OPEN |
رقم الأكسشن: | edsair.doi.dedup.....cb7f060666e02e4a11b1bf3fd684ecb3 |
قاعدة البيانات: | OpenAIRE |
تدمد: | 10290389 00958972 |
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