Metal–Acid Synergy: Hydrodeoxygenation of Anisole over Pt/Al‐SBA‐15
| العنوان: | Metal–Acid Synergy: Hydrodeoxygenation of Anisole over Pt/Al‐SBA‐15 |
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| المؤلفون: | Karen Wilson, Mark A. Isaacs, Atal Shivhare, Christopher M. A. Parlett, Adam F. Lee, James A. Hunns, Lee J. Durndell |
| المصدر: | ChemSusChem. 13:4775-4775 |
| بيانات النشر: | Wiley, 2020. |
| سنة النشر: | 2020 |
| مصطلحات موضوعية: | General Chemical Engineering, chemistry.chemical_element, 02 engineering and technology, 010402 general chemistry, 021001 nanoscience & nanotechnology, Anisole, Heterogeneous catalysis, Platinum nanoparticles, 01 natural sciences, 0104 chemical sciences, Catalysis, chemistry.chemical_compound, General Energy, chemistry, Lignin, Organic chemistry, Environmental Chemistry, General Materials Science, 0210 nano-technology, Platinum, Brønsted–Lowry acid–base theory, Hydrodeoxygenation |
| الوصف: | Hydrodeoxygenation (HDO) is a promising technology to upgrade fast pyrolysis bio-oils but it requires active and selective catalysts. Here we explore the synergy between the metal and acid sites in the HDO of anisole, a model pyrolysis bio-oil compound, over mono- and bi-functional Pt/(Al)-SBA-15 catalysts. Ring hydrogenation of anisole to methoxycyclohexane occurs over metal sites and is structure sensitive; it is favored over small (4 nm) Pt nanoparticles, which confer a turnover frequency (TOF) of approximately 2000 h |
| تدمد: | 1864-564X 1864-5631 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e8d98de6ffddaa6e8a2ff958daf0339c https://doi.org/10.1002/cssc.202002011 |
| حقوق: | OPEN |
| رقم الأكسشن: | edsair.doi.dedup.....e8d98de6ffddaa6e8a2ff958daf0339c |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 1864564X 18645631 |
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