Optimization of permanently polarized hydroxyapatite catalyst. Implications for the electrophotosynthesis of amino acids by nitrogen and carbon fixation
| العنوان: | Optimization of permanently polarized hydroxyapatite catalyst. Implications for the electrophotosynthesis of amino acids by nitrogen and carbon fixation |
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| المؤلفون: | Carlos Alemán, Vanesa Sanz, Pau Turon, Luis J. del Valle, Jordi Puiggalí, Jordi Sans |
| المساهمون: | Universitat Politècnica de Catalunya. Doctorat en Polímers i Biopolímers, Universitat Politècnica de Catalunya. Departament d'Enginyeria Química, Universitat Politècnica de Catalunya. PSEP - Polimers Sintètics: Estructura i Propietats. Polimers Biodegradables, Universitat Politècnica de Catalunya. IMEM-BRT- Innovation in Materials and Molecular Engineering - Biomaterials for Regenerative Therapies |
| المصدر: | UPCommons. Portal del coneixement obert de la UPC Universitat Politècnica de Catalunya (UPC) |
| بيانات النشر: | Elsevier BV, 2021. |
| سنة النشر: | 2021 |
| مصطلحات موضوعية: | Chemistry, Carbon fixation, chemistry.chemical_element, Phosphate, Nitrogen, Catalysis, Crystallinity, chemistry.chemical_compound, Enginyeria química [Àrees temàtiques de la UPC], Catàlisi, Chemical engineering, Phase (matter), Brushite, Physical and Theoretical Chemistry, Polarization (electrochemistry) |
| الوصف: | The enhanced catalytic activity of permanently polarized hydroxyapatite, which is achieved using a thermally stimulated polarization process, largely depends on both the experimental conditions used to prepare crystalline hydroxyapatite from its calcium and phosphate precursors and the polarization process parameters. A mineral similar to brushite, which is an apatitic phase that can evolve to hydroxyapatite, is found at the surface of highly crystalline hydroxyapatite. It appears after chemical precipitation and hydrothermal treatment performed at 150 °C for 24 h followed by a sinterization at 1000 °C and a polarization treatment by applying a voltage of 500 V at high temperature. Both the high crystallinity and the presence of brushite-like phase on the electrophotocatalyst affect the nitrogen and carbon fixation under mild reaction conditions (95 °C and 6 bar) and the synthesis of glycine and alanine from a simple gas mixture containing N2, CO2, CH4 and H2O. Thus, the Gly/Ala ratio can be customized by controlling the presence of brushite on the surface of the catalyst, enabling to develop new strategies to regulate the production of amino acids by nitrogen and carbon fixation. |
| وصف الملف: | application/pdf |
| تدمد: | 0021-9517 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f6b0f052e1823595ccd66822656cbbc0 https://doi.org/10.1016/j.jcat.2021.03.023 |
| حقوق: | OPEN |
| رقم الأكسشن: | edsair.doi.dedup.....f6b0f052e1823595ccd66822656cbbc0 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 00219517 |
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