Retro-biosynthetic construction of corynanthe alkaloid skeletons from rhynchophylline alkaloids
| العنوان: | Retro-biosynthetic construction of corynanthe alkaloid skeletons from rhynchophylline alkaloids |
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| المؤلفون: | Xiaogang Tong, Bingfei Shi, Chengfeng Xia, Qian Liu, Yanman Huo |
| المصدر: | Organic & Biomolecular Chemistry. 17:8062-8066 |
| بيانات النشر: | Royal Society of Chemistry (RSC), 2019. |
| سنة النشر: | 2019 |
| مصطلحات موضوعية: | biology, 010405 organic chemistry, Chemistry, Stereochemistry, Alkaloid, Organic Chemistry, 010402 general chemistry, biology.organism_classification, 01 natural sciences, Biochemistry, 0104 chemical sciences, Corynanthe, Rhynchophylline, Physical and Theoretical Chemistry |
| الوصف: | Rhynchophylline alkaloids are bio-synthesized from corynanthe alkaloids via an oxidative rearrangement. We demonstrate here that corynanthe alkaloids could be generated from rhynchophylline alkaloids in a retro-biosynthetic manner via a Wagner-Meerwein rearrangement. A series of corynanthe analogues were afforded with good functional group tolerance and satisfactory yields. |
| تدمد: | 1477-0539 1477-0520 |
| URL الوصول: | https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fdc94ce6ca10998353b2ca8c534f12d3 https://doi.org/10.1039/c9ob01740b |
| حقوق: | CLOSED |
| رقم الأكسشن: | edsair.doi.dedup.....fdc94ce6ca10998353b2ca8c534f12d3 |
| قاعدة البيانات: | OpenAIRE |
| تدمد: | 14770539 14770520 |
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