[Syntheses and spectral study of novel metal zinc organic phosphonate]
العنوان: | [Syntheses and spectral study of novel metal zinc organic phosphonate] |
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المؤلفون: | Rui-qing, Sun, Jin, Hu, Han-hui, Zhang, Yan-ning, Cao, Zhi-bin, Ye, Ye-qin, Wang, Yi-ping, Chen |
المصدر: | Guang pu xue yu guang pu fen xi = Guang pu. 30(8) |
سنة النشر: | 2010 |
الوصف: | Two novel Zn2+ organic phosphonate Zn(4,4'-bipy)(HBCP) 1 and [Zn2 (phen)2 (BCP)(H2 BCP)].H2O2 were hydrothermally synthesized. The compound 1 is with two-dimensional layer framework whereas the compound 2 is zero-dimensional structure. The Zn2+ ion is four-coordinated in compound 1 while five or six-coordinated in compound 2. The relationship between their properties and structures was studied by using FTIR, two-dimensional (2D) correlation infrared spectroscopy under thermal perturbation, fluorescence and UV-Vis DRS spectrum etc. Upon light excitation at 350 nm, the compound 1 exhibits luminescence with a strong wide emission at 412 nm and a weak emission at 520 nm, while the compound 2 exhibits luminescence with a wide emission only at 398 nm under light excitation at 336 nm. |
تدمد: | 1000-0593 |
URL الوصول: | https://explore.openaire.eu/search/publication?articleId=pmid________::bc66480657c09e621a3a2d0a5c0bc125 https://pubmed.ncbi.nlm.nih.gov/20939342 |
رقم الأكسشن: | edsair.pmid..........bc66480657c09e621a3a2d0a5c0bc125 |
قاعدة البيانات: | OpenAIRE |
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